SYNTHESIS AND CRYSTAL STRUCTURE OF PENTANUCLEAR HETEROMETALLIC Pd(II)–La(III) ACETATE COMPLEX

The structure of a novel pentanuclear heterometallic complex [Pd 3 La 2 (OOCMe) 12 (MeCOOH) 4 ] with an unusual ratio of metals 3Pd:2La is studied by XRD. The complex is prepared by the reaction of palladium acetate [Pd 3 (OOCMe) 6 ] with lanthanum acetate [La(OOCMe) 3 ·1.5H 2 O]. The molecule of th...

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Bibliographic Details
Published in:Journal of structural chemistry 2021-10, Vol.62 (10), p.1511-1515
Main Authors: Yakushev, I. A., Dyuzheva, M. A., Cherkashina, N. V., Kornev, A. B., Smirnova, N. S., Vargaftik, M. N.
Format: Article
Language:English
Subjects:
Acetic acid
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Crystal structure
Crystals
Hydrogen bonds
Inorganic Chemistry
Lanthanum
Molecular
Optical and Plasma Physics
Palladium
Physical Chemistry
Solid State Physics
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Summary:The structure of a novel pentanuclear heterometallic complex [Pd 3 La 2 (OOCMe) 12 (MeCOOH) 4 ] with an unusual ratio of metals 3Pd:2La is studied by XRD. The complex is prepared by the reaction of palladium acetate [Pd 3 (OOCMe) 6 ] with lanthanum acetate [La(OOCMe) 3 ·1.5H 2 O]. The molecule of the complex contains two heterometallic binuclear fragments [PdLa(OOCMe) 5 (MeCOOH) 2 ] connected to the structure-forming fragment [Pd(OOCMe) 2 ] via bridging acetate groups and hydrogen bonds of coordinated acetic acid.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476621100048