Effect of steam on coke deposition during the tar reforming from corn straw pyrolysis over biochar

• Published in: Fuel processing technology 2021-12, Vol.224, p.107007, Article 107007
• Main Authors: Sun, Hongliang, Feng, Dongdong, Sun, Shaozeng, Wei, Qingyu, Zhao, Yijun, Zhang, Yu, Xie, Min, Qin, Yukun
• Format: Article
• Language: English
• Subjects: Biochar; Coke; Coke deposition; Combustion; Deposition; Fixed bed reactors; Fixed beds; Fluidized beds; Gas composition; Hydrogen production; Pyrolysis; Reforming; Steam; Tar reforming
• ISSN: 0378-3820; 1873-7188
• DOI: 10.1016/j.fuproc.2021.107007

Coke deposition is a critical issue for catalysts in tar reforming. Steam is conducive to tar removal and hydrogen production in biomass pyrolysis, while its effect on coke formation is not well known. Thus, a two-stage fluidized bed/fixed bed reactor was used to study the effect of steam addition on coke deposition. The primary conclusions are as follows: combining steam and biochar, the tar removal efficiency is more than 90% within 20 min of time on stream (TOS). After the TOS reaches 30 min, the biochar surface is saturated with coke deposition and the specific surface area of the biochar stops decreasing. The addition of steam leads to a reduction in the combustion reactivity of the biochar. Besides, the aromatization of the biochar increase and the number of O-containing structures decreases. For the tar, the addition of steam reduces the aliphatics content and increases the O-containing aromatics content. For the gas composition, the addition of steam results in the decrease of CH4 yield while the H2 yield increases to 0.12 L/g. The H/C atomic ratio of the gas composition decreases while the O/C atomic ratio increases. The active coke is consumed and decomposed after the introduction of steam. The remaining coke is dominated by inert coke. This contributes to the relatively developed pore structure but a weakened combustion reactivity of biochar. [Display omitted] •The coke growth rapidly reaches the saturation limit in the presence of steam.•The addition of steam reduces the reactivity and O-containing structures of biochar.•The aromaticity of the tar is enhanced after reforming in the presence of steam.•The addition of steam leads to the reduction in CH4 yield and increase in H2 yield.•The active coke is decomposed after the introduction of steam.