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Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior
Two poly-iodine aromatic tricarboxylate complexes: {(Me 2 NH 2 )[Mn(TIBTC)(2, 2'-bipy)(H 2 O)]} n ( 1 ) and {(Me 2 NH 2 )[Co(TIBTC)(DMA)]} n ( 2 ) (DMA = N , N -dimethylacetamide), were designed and synthesized by the hydrothermal synthetic methods (TIBTC = 2, 4, 6-triiodo-1, 3, 5-benzenetrica...
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| Published in: | Transition metal chemistry (Weinheim) 2021-12, Vol.46 (8), p.633-644 |
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| Main Authors: | , , , , , , |
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| cites | cdi_FETCH-LOGICAL-c319t-625ce7b7919e3d2ba37aaea4d3597ebffeff5e6afcac02577139e64b437a03673 |
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| container_issue | 8 |
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| container_title | Transition metal chemistry (Weinheim) |
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| creator | Cai, He-Qun Liu, Chun-Hong Xin, Yu Wang, Chen Bai, Feng-Ying Sun, Li-Xian Xing, Yong-Heng |
| description | Two poly-iodine aromatic tricarboxylate complexes: {(Me
2
NH
2
)[Mn(TIBTC)(2, 2'-bipy)(H
2
O)]}
n
(
1
) and {(Me
2
NH
2
)[Co(TIBTC)(DMA)]}
n
(
2
) (DMA =
N
,
N
-dimethylacetamide), were designed and synthesized by the hydrothermal synthetic methods (TIBTC = 2, 4, 6-triiodo-1, 3, 5-benzenetricarboxylic acid). Complexes were characterized by microanalysis. The crystal structures of complexes
1
and
2
were determined by X-ray single-crystal diffraction. Complex
1
is a 3D network supramolecular network structure connected by the hydrogen bonds, and complex
2
is a 3D network structure. To explore their functional properties, we first investigated the adsorption capacity of complexes
1
and
2
for iodine capture in cyclohexane solution. The maximum adsorption capacity of complex
2
is 125 mg/g. Meanwhile, the adsorption kinetic curves fitting showed that complexes
1
and
2
all conformed to the pseudo-second-order curves. |
| doi_str_mv | 10.1007/s11243-021-00481-5 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2602033697</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2602033697</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-625ce7b7919e3d2ba37aaea4d3597ebffeff5e6afcac02577139e64b437a03673</originalsourceid><addsrcrecordid>eNp9kDtPwzAURi0EEqXwB5gsMZtev-JmRBEvqYgFJDbjODaktHGwUyD_nrQBsTHd5ZzvSgehUwrnFEDNEqVMcAKMEgAxp0TuoQmVipEc6NM-mgAXQASby0N0lNISACRTYoKei9CkLm5sV4cGB4_bsOpJHaq6cdjEsDZdbbE1sQxf_cp0Dt81syJgH83afYb4lrBpKvwrVCnEdjdVulfzUYd4jA68WSV38nOn6PHq8qG4IYv769viYkEsp3lHMiatU6XKae54xUrDlTHOiIrLXLnSe-e9dJnx1lhgUinKc5eJUgwc8EzxKTobd9sY3jcudXoZNrEZXmqWAQPOs3xLsZGyMaQUnddtrNcm9pqC3pbUY0k9lNS7kloOEh-lNMDNi4t_0_9Y3yojeEs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2602033697</pqid></control><display><type>article</type><title>Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior</title><source>Springer Link</source><creator>Cai, He-Qun ; Liu, Chun-Hong ; Xin, Yu ; Wang, Chen ; Bai, Feng-Ying ; Sun, Li-Xian ; Xing, Yong-Heng</creator><creatorcontrib>Cai, He-Qun ; Liu, Chun-Hong ; Xin, Yu ; Wang, Chen ; Bai, Feng-Ying ; Sun, Li-Xian ; Xing, Yong-Heng</creatorcontrib><description>Two poly-iodine aromatic tricarboxylate complexes: {(Me
2
NH
2
)[Mn(TIBTC)(2, 2'-bipy)(H
2
O)]}
n
(
1
) and {(Me
2
NH
2
)[Co(TIBTC)(DMA)]}
n
(
2
) (DMA =
N
,
N
-dimethylacetamide), were designed and synthesized by the hydrothermal synthetic methods (TIBTC = 2, 4, 6-triiodo-1, 3, 5-benzenetricarboxylic acid). Complexes were characterized by microanalysis. The crystal structures of complexes
1
and
2
were determined by X-ray single-crystal diffraction. Complex
1
is a 3D network supramolecular network structure connected by the hydrogen bonds, and complex
2
is a 3D network structure. To explore their functional properties, we first investigated the adsorption capacity of complexes
1
and
2
for iodine capture in cyclohexane solution. The maximum adsorption capacity of complex
2
is 125 mg/g. Meanwhile, the adsorption kinetic curves fitting showed that complexes
1
and
2
all conformed to the pseudo-second-order curves.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-021-00481-5</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Adsorption ; Catalysis ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystals ; Curve fitting ; Cyclohexane ; Dimethyl acetamide ; Hydrogen bonds ; Inorganic Chemistry ; Iodine ; Organometallic Chemistry ; Physical Chemistry ; Single crystals</subject><ispartof>Transition metal chemistry (Weinheim), 2021-12, Vol.46 (8), p.633-644</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-625ce7b7919e3d2ba37aaea4d3597ebffeff5e6afcac02577139e64b437a03673</citedby><cites>FETCH-LOGICAL-c319t-625ce7b7919e3d2ba37aaea4d3597ebffeff5e6afcac02577139e64b437a03673</cites><orcidid>0000-0001-6202-054X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Cai, He-Qun</creatorcontrib><creatorcontrib>Liu, Chun-Hong</creatorcontrib><creatorcontrib>Xin, Yu</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Bai, Feng-Ying</creatorcontrib><creatorcontrib>Sun, Li-Xian</creatorcontrib><creatorcontrib>Xing, Yong-Heng</creatorcontrib><title>Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transit Met Chem</addtitle><description>Two poly-iodine aromatic tricarboxylate complexes: {(Me
2
NH
2
)[Mn(TIBTC)(2, 2'-bipy)(H
2
O)]}
n
(
1
) and {(Me
2
NH
2
)[Co(TIBTC)(DMA)]}
n
(
2
) (DMA =
N
,
N
-dimethylacetamide), were designed and synthesized by the hydrothermal synthetic methods (TIBTC = 2, 4, 6-triiodo-1, 3, 5-benzenetricarboxylic acid). Complexes were characterized by microanalysis. The crystal structures of complexes
1
and
2
were determined by X-ray single-crystal diffraction. Complex
1
is a 3D network supramolecular network structure connected by the hydrogen bonds, and complex
2
is a 3D network structure. To explore their functional properties, we first investigated the adsorption capacity of complexes
1
and
2
for iodine capture in cyclohexane solution. The maximum adsorption capacity of complex
2
is 125 mg/g. Meanwhile, the adsorption kinetic curves fitting showed that complexes
1
and
2
all conformed to the pseudo-second-order curves.</description><subject>Adsorption</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Curve fitting</subject><subject>Cyclohexane</subject><subject>Dimethyl acetamide</subject><subject>Hydrogen bonds</subject><subject>Inorganic Chemistry</subject><subject>Iodine</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kDtPwzAURi0EEqXwB5gsMZtev-JmRBEvqYgFJDbjODaktHGwUyD_nrQBsTHd5ZzvSgehUwrnFEDNEqVMcAKMEgAxp0TuoQmVipEc6NM-mgAXQASby0N0lNISACRTYoKei9CkLm5sV4cGB4_bsOpJHaq6cdjEsDZdbbE1sQxf_cp0Dt81syJgH83afYb4lrBpKvwrVCnEdjdVulfzUYd4jA68WSV38nOn6PHq8qG4IYv769viYkEsp3lHMiatU6XKae54xUrDlTHOiIrLXLnSe-e9dJnx1lhgUinKc5eJUgwc8EzxKTobd9sY3jcudXoZNrEZXmqWAQPOs3xLsZGyMaQUnddtrNcm9pqC3pbUY0k9lNS7kloOEh-lNMDNi4t_0_9Y3yojeEs</recordid><startdate>20211201</startdate><enddate>20211201</enddate><creator>Cai, He-Qun</creator><creator>Liu, Chun-Hong</creator><creator>Xin, Yu</creator><creator>Wang, Chen</creator><creator>Bai, Feng-Ying</creator><creator>Sun, Li-Xian</creator><creator>Xing, Yong-Heng</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-6202-054X</orcidid></search><sort><creationdate>20211201</creationdate><title>Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior</title><author>Cai, He-Qun ; Liu, Chun-Hong ; Xin, Yu ; Wang, Chen ; Bai, Feng-Ying ; Sun, Li-Xian ; Xing, Yong-Heng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-625ce7b7919e3d2ba37aaea4d3597ebffeff5e6afcac02577139e64b437a03673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Adsorption</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Curve fitting</topic><topic>Cyclohexane</topic><topic>Dimethyl acetamide</topic><topic>Hydrogen bonds</topic><topic>Inorganic Chemistry</topic><topic>Iodine</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cai, He-Qun</creatorcontrib><creatorcontrib>Liu, Chun-Hong</creatorcontrib><creatorcontrib>Xin, Yu</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Bai, Feng-Ying</creatorcontrib><creatorcontrib>Sun, Li-Xian</creatorcontrib><creatorcontrib>Xing, Yong-Heng</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cai, He-Qun</au><au>Liu, Chun-Hong</au><au>Xin, Yu</au><au>Wang, Chen</au><au>Bai, Feng-Ying</au><au>Sun, Li-Xian</au><au>Xing, Yong-Heng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transit Met Chem</stitle><date>2021-12-01</date><risdate>2021</risdate><volume>46</volume><issue>8</issue><spage>633</spage><epage>644</epage><pages>633-644</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>Two poly-iodine aromatic tricarboxylate complexes: {(Me
2
NH
2
)[Mn(TIBTC)(2, 2'-bipy)(H
2
O)]}
n
(
1
) and {(Me
2
NH
2
)[Co(TIBTC)(DMA)]}
n
(
2
) (DMA =
N
,
N
-dimethylacetamide), were designed and synthesized by the hydrothermal synthetic methods (TIBTC = 2, 4, 6-triiodo-1, 3, 5-benzenetricarboxylic acid). Complexes were characterized by microanalysis. The crystal structures of complexes
1
and
2
were determined by X-ray single-crystal diffraction. Complex
1
is a 3D network supramolecular network structure connected by the hydrogen bonds, and complex
2
is a 3D network structure. To explore their functional properties, we first investigated the adsorption capacity of complexes
1
and
2
for iodine capture in cyclohexane solution. The maximum adsorption capacity of complex
2
is 125 mg/g. Meanwhile, the adsorption kinetic curves fitting showed that complexes
1
and
2
all conformed to the pseudo-second-order curves.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11243-021-00481-5</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-6202-054X</orcidid></addata></record> |
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| issn | 0340-4285 1572-901X |
| language | eng |
| recordid | cdi_proquest_journals_2602033697 |
| source | Springer Link |
| subjects | Adsorption Catalysis Chemistry Chemistry and Materials Science Crystal structure Crystals Curve fitting Cyclohexane Dimethyl acetamide Hydrogen bonds Inorganic Chemistry Iodine Organometallic Chemistry Physical Chemistry Single crystals |
| title | Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior |
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