Cerium(IV) Orthophosphates (Review)

The review analyzes the data on the composition, structure, and properties of amorphous and crystalline cerium(IV) orthophosphates published between 1882 and 2020. The review includes information on Ce(IV) complexation in aqueous solutions, formation conditions and characteristics of amorphous inorg...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2021-12, Vol.66 (12), p.1761-1778
Main Authors: Kozlova, T. O., Baranchikov, A. E., Ivanov, V. K.
Format: Article
Language:English
Subjects:
Aqueous solutions
Cerium
Chemistry
Chemistry and Materials Science
Crystal structure
Crystallinity
Inorganic Chemistry
Synthesis and Properties of Inorganic Compounds
Thorium
Uranium
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Summary:The review analyzes the data on the composition, structure, and properties of amorphous and crystalline cerium(IV) orthophosphates published between 1882 and 2020. The review includes information on Ce(IV) complexation in aqueous solutions, formation conditions and characteristics of amorphous inorganic and organo-inorganic cerium(IV) hydrogen orthophosphates, and structural diversity of crystalline cerium(IV) orthophosphates. Formation conditions and structure of the closest chemical analogs of cerium(IV) orthophosphates, Group IV metal and actinide (thorium and uranium) orthophosphates, have been compared for the first time; the comparison provided a basis to assess the possibilities to prepare isostructural cerium(IV) compounds unknown to date.
ISSN:0036-0236
1531-8613
DOI:10.1134/S003602362112010X