A NOVEL MERCURY COORDINATION COMPOUND WITH YELLOW PHOTOLUMINESCENCE

The solvothermal reaction of 4,4′-bipyridine (Bipy) and mercury nitrate in a mixed acetonitrile/water solution leads to a novel mercury coordination compound with the in situ formation of cyanide ions Hg(Bipy)(CN) 2 ( 1 ). Its structure is determined by single crystal X-ray diffraction (XRD), and fu...

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Bibliographic Details
Published in:Journal of structural chemistry 2021-11, Vol.62 (11), p.1810-1817
Main Authors: Tao, Y. -L., Zhu, Z. -H., Zhao, Z., Zhu, Q. -T., Wang, O., Liu, X.
Format: Article
Language:English
Subjects:
Acetonitrile
Atomic
Atomic/Molecular Structure and Spectra
Chemical analysis
Chemistry
Chemistry and Materials Science
Coordination compounds
Crystal structure
Infrared analysis
Infrared spectroscopy
Inorganic Chemistry
Mercury compounds
Molecular
Optical and Plasma Physics
Photoluminescence
Physical Chemistry
Single crystals
Solid State Physics
X-ray diffraction
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Summary:The solvothermal reaction of 4,4′-bipyridine (Bipy) and mercury nitrate in a mixed acetonitrile/water solution leads to a novel mercury coordination compound with the in situ formation of cyanide ions Hg(Bipy)(CN) 2 ( 1 ). Its structure is determined by single crystal X-ray diffraction (XRD), and further characterized by powder XRD, elemental analysis, and IR spectroscopy. Compound 1 exhibits a 1D zigzag [Hg(Bipy)(CN) 2 ] n chain structure. The solid-state photoluminescent properties of 1 are also investigated.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476621110184