A molecular beam-surface apparatus for quantum state-resolved adsorption studies

Understanding the microscopic mechanism of molecule–surface interaction is of great importance in the study of chemical dynamics. Yet, it remains challenging to experimentally acquire quantum state resolved results, particularly the results related to different degrees of freedom of the reactants. H...

Full description

Saved in:
Bibliographic Details
Published in:Review of scientific instruments 2022-01, Vol.93 (1), p.013201-013201
Main Authors: Shen, Qiqi, Wu, Jiawei, Zhou, Feiyue, Song, Yunlong, Dong, Wenrui, Wang, Xingan, Wang, Tao, Yang, Xueming
Format: Article
Language:English
Subjects:
Adsorption
Degrees of freedom
Hydrogen chloride
Infrared lasers
Molecular beams
Scientific apparatus & instruments
Surface chemistry
Surface dynamics
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c383t-8b6add944525c36993e66efa5b6c2b7b4935953e1d9aaf70b7501f2f4c7853fe3
cites cdi_FETCH-LOGICAL-c383t-8b6add944525c36993e66efa5b6c2b7b4935953e1d9aaf70b7501f2f4c7853fe3
container_end_page 013201
container_issue 1
container_start_page 013201
container_title Review of scientific instruments
container_volume 93
creator Shen, Qiqi
Wu, Jiawei
Zhou, Feiyue
Song, Yunlong
Dong, Wenrui
Wang, Xingan
Wang, Tao
Yang, Xueming
description Understanding the microscopic mechanism of molecule–surface interaction is of great importance in the study of chemical dynamics. Yet, it remains challenging to experimentally acquire quantum state resolved results, particularly the results related to different degrees of freedom of the reactants. Here, we report the design and performance of a new apparatus for molecule–surface dynamics studies, which enable the measurement of quantum state-resolved adsorption. A continuous narrow-linewidth infrared laser source and molecular beam unit were developed and employed in this new apparatus to achieve independent control on different degrees of freedom (translation, vibration, and rotation) of the molecule. Preliminary results on hydrogen and hydrogen chloride adsorption on the Cu (111) surface were also presented.
doi_str_mv 10.1063/5.0049178
format article
fullrecord <record><control><sourceid>proquest_scita</sourceid><recordid>TN_cdi_proquest_journals_2616104955</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2624950891</sourcerecordid><originalsourceid>FETCH-LOGICAL-c383t-8b6add944525c36993e66efa5b6c2b7b4935953e1d9aaf70b7501f2f4c7853fe3</originalsourceid><addsrcrecordid>eNp90E1LwzAYwPEgipvTg19ACl5U6EyalzbHMXyDgR70XNL0CXS0TZc0gt_ejE0FQXPJIb_nIfwROid4TrCgt3yOMZMkLw7QlOBCprnI6CGaYkxZKnJWTNCJ92scDyfkGE0oJ3GAkSl6WSSdbUGHVrmkAtWlPjijNCRqGJRTY_CJsS7ZBNWPoUv8qEZIHXjbvkOdqNpbN4yN7eNLqBvwp-jIqNbD2f6eobf7u9flY7p6fnhaLlappgUd06ISqq4lYzzjmgopKQgBRvFK6KzKKyYpl5wCqaVSJsdVzjExmWE6Lzg1QGfoard3cHYTwI9l13gNbat6sMGXmciY5DEGifTyF13b4Pr4u6iI2KbgPKrrndLOeu_AlINrOuU-SoLLbeaSl_vM0V7sN4aqg_pbfnWN4GYHvG5isdjn321_4nfrfmA51IZ-AnopkxU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2616104955</pqid></control><display><type>article</type><title>A molecular beam-surface apparatus for quantum state-resolved adsorption studies</title><source>American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)</source><source>AIP - American Institute of Physics</source><creator>Shen, Qiqi ; Wu, Jiawei ; Zhou, Feiyue ; Song, Yunlong ; Dong, Wenrui ; Wang, Xingan ; Wang, Tao ; Yang, Xueming</creator><creatorcontrib>Shen, Qiqi ; Wu, Jiawei ; Zhou, Feiyue ; Song, Yunlong ; Dong, Wenrui ; Wang, Xingan ; Wang, Tao ; Yang, Xueming</creatorcontrib><description>Understanding the microscopic mechanism of molecule–surface interaction is of great importance in the study of chemical dynamics. Yet, it remains challenging to experimentally acquire quantum state resolved results, particularly the results related to different degrees of freedom of the reactants. Here, we report the design and performance of a new apparatus for molecule–surface dynamics studies, which enable the measurement of quantum state-resolved adsorption. A continuous narrow-linewidth infrared laser source and molecular beam unit were developed and employed in this new apparatus to achieve independent control on different degrees of freedom (translation, vibration, and rotation) of the molecule. Preliminary results on hydrogen and hydrogen chloride adsorption on the Cu (111) surface were also presented.</description><identifier>ISSN: 0034-6748</identifier><identifier>EISSN: 1089-7623</identifier><identifier>DOI: 10.1063/5.0049178</identifier><identifier>PMID: 35104941</identifier><identifier>CODEN: RSINAK</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>Adsorption ; Degrees of freedom ; Hydrogen chloride ; Infrared lasers ; Molecular beams ; Scientific apparatus &amp; instruments ; Surface chemistry ; Surface dynamics</subject><ispartof>Review of scientific instruments, 2022-01, Vol.93 (1), p.013201-013201</ispartof><rights>Author(s)</rights><rights>2022 Author(s). Published under an exclusive license by AIP Publishing.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-8b6add944525c36993e66efa5b6c2b7b4935953e1d9aaf70b7501f2f4c7853fe3</citedby><cites>FETCH-LOGICAL-c383t-8b6add944525c36993e66efa5b6c2b7b4935953e1d9aaf70b7501f2f4c7853fe3</cites><orcidid>0000-0001-5414-4534 ; 0000-0001-6684-9187 ; 0000-0002-1206-7021 ; 0000-0002-3640-1821 ; 0000-0002-6091-1020 ; 0000000236401821 ; 0000000260911020 ; 0000000154144534 ; 0000000212067021 ; 0000000166849187</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/rsi/article-lookup/doi/10.1063/5.0049178$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>314,780,782,784,795,27924,27925,76383</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35104941$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shen, Qiqi</creatorcontrib><creatorcontrib>Wu, Jiawei</creatorcontrib><creatorcontrib>Zhou, Feiyue</creatorcontrib><creatorcontrib>Song, Yunlong</creatorcontrib><creatorcontrib>Dong, Wenrui</creatorcontrib><creatorcontrib>Wang, Xingan</creatorcontrib><creatorcontrib>Wang, Tao</creatorcontrib><creatorcontrib>Yang, Xueming</creatorcontrib><title>A molecular beam-surface apparatus for quantum state-resolved adsorption studies</title><title>Review of scientific instruments</title><addtitle>Rev Sci Instrum</addtitle><description>Understanding the microscopic mechanism of molecule–surface interaction is of great importance in the study of chemical dynamics. Yet, it remains challenging to experimentally acquire quantum state resolved results, particularly the results related to different degrees of freedom of the reactants. Here, we report the design and performance of a new apparatus for molecule–surface dynamics studies, which enable the measurement of quantum state-resolved adsorption. A continuous narrow-linewidth infrared laser source and molecular beam unit were developed and employed in this new apparatus to achieve independent control on different degrees of freedom (translation, vibration, and rotation) of the molecule. Preliminary results on hydrogen and hydrogen chloride adsorption on the Cu (111) surface were also presented.</description><subject>Adsorption</subject><subject>Degrees of freedom</subject><subject>Hydrogen chloride</subject><subject>Infrared lasers</subject><subject>Molecular beams</subject><subject>Scientific apparatus &amp; instruments</subject><subject>Surface chemistry</subject><subject>Surface dynamics</subject><issn>0034-6748</issn><issn>1089-7623</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp90E1LwzAYwPEgipvTg19ACl5U6EyalzbHMXyDgR70XNL0CXS0TZc0gt_ejE0FQXPJIb_nIfwROid4TrCgt3yOMZMkLw7QlOBCprnI6CGaYkxZKnJWTNCJ92scDyfkGE0oJ3GAkSl6WSSdbUGHVrmkAtWlPjijNCRqGJRTY_CJsS7ZBNWPoUv8qEZIHXjbvkOdqNpbN4yN7eNLqBvwp-jIqNbD2f6eobf7u9flY7p6fnhaLlappgUd06ISqq4lYzzjmgopKQgBRvFK6KzKKyYpl5wCqaVSJsdVzjExmWE6Lzg1QGfoard3cHYTwI9l13gNbat6sMGXmciY5DEGifTyF13b4Pr4u6iI2KbgPKrrndLOeu_AlINrOuU-SoLLbeaSl_vM0V7sN4aqg_pbfnWN4GYHvG5isdjn321_4nfrfmA51IZ-AnopkxU</recordid><startdate>20220101</startdate><enddate>20220101</enddate><creator>Shen, Qiqi</creator><creator>Wu, Jiawei</creator><creator>Zhou, Feiyue</creator><creator>Song, Yunlong</creator><creator>Dong, Wenrui</creator><creator>Wang, Xingan</creator><creator>Wang, Tao</creator><creator>Yang, Xueming</creator><general>American Institute of Physics</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-5414-4534</orcidid><orcidid>https://orcid.org/0000-0001-6684-9187</orcidid><orcidid>https://orcid.org/0000-0002-1206-7021</orcidid><orcidid>https://orcid.org/0000-0002-3640-1821</orcidid><orcidid>https://orcid.org/0000-0002-6091-1020</orcidid><orcidid>https://orcid.org/0000000236401821</orcidid><orcidid>https://orcid.org/0000000260911020</orcidid><orcidid>https://orcid.org/0000000154144534</orcidid><orcidid>https://orcid.org/0000000212067021</orcidid><orcidid>https://orcid.org/0000000166849187</orcidid></search><sort><creationdate>20220101</creationdate><title>A molecular beam-surface apparatus for quantum state-resolved adsorption studies</title><author>Shen, Qiqi ; Wu, Jiawei ; Zhou, Feiyue ; Song, Yunlong ; Dong, Wenrui ; Wang, Xingan ; Wang, Tao ; Yang, Xueming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-8b6add944525c36993e66efa5b6c2b7b4935953e1d9aaf70b7501f2f4c7853fe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorption</topic><topic>Degrees of freedom</topic><topic>Hydrogen chloride</topic><topic>Infrared lasers</topic><topic>Molecular beams</topic><topic>Scientific apparatus &amp; instruments</topic><topic>Surface chemistry</topic><topic>Surface dynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shen, Qiqi</creatorcontrib><creatorcontrib>Wu, Jiawei</creatorcontrib><creatorcontrib>Zhou, Feiyue</creatorcontrib><creatorcontrib>Song, Yunlong</creatorcontrib><creatorcontrib>Dong, Wenrui</creatorcontrib><creatorcontrib>Wang, Xingan</creatorcontrib><creatorcontrib>Wang, Tao</creatorcontrib><creatorcontrib>Yang, Xueming</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Review of scientific instruments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shen, Qiqi</au><au>Wu, Jiawei</au><au>Zhou, Feiyue</au><au>Song, Yunlong</au><au>Dong, Wenrui</au><au>Wang, Xingan</au><au>Wang, Tao</au><au>Yang, Xueming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A molecular beam-surface apparatus for quantum state-resolved adsorption studies</atitle><jtitle>Review of scientific instruments</jtitle><addtitle>Rev Sci Instrum</addtitle><date>2022-01-01</date><risdate>2022</risdate><volume>93</volume><issue>1</issue><spage>013201</spage><epage>013201</epage><pages>013201-013201</pages><issn>0034-6748</issn><eissn>1089-7623</eissn><coden>RSINAK</coden><abstract>Understanding the microscopic mechanism of molecule–surface interaction is of great importance in the study of chemical dynamics. Yet, it remains challenging to experimentally acquire quantum state resolved results, particularly the results related to different degrees of freedom of the reactants. Here, we report the design and performance of a new apparatus for molecule–surface dynamics studies, which enable the measurement of quantum state-resolved adsorption. A continuous narrow-linewidth infrared laser source and molecular beam unit were developed and employed in this new apparatus to achieve independent control on different degrees of freedom (translation, vibration, and rotation) of the molecule. Preliminary results on hydrogen and hydrogen chloride adsorption on the Cu (111) surface were also presented.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>35104941</pmid><doi>10.1063/5.0049178</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-5414-4534</orcidid><orcidid>https://orcid.org/0000-0001-6684-9187</orcidid><orcidid>https://orcid.org/0000-0002-1206-7021</orcidid><orcidid>https://orcid.org/0000-0002-3640-1821</orcidid><orcidid>https://orcid.org/0000-0002-6091-1020</orcidid><orcidid>https://orcid.org/0000000236401821</orcidid><orcidid>https://orcid.org/0000000260911020</orcidid><orcidid>https://orcid.org/0000000154144534</orcidid><orcidid>https://orcid.org/0000000212067021</orcidid><orcidid>https://orcid.org/0000000166849187</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0034-6748
ispartof Review of scientific instruments, 2022-01, Vol.93 (1), p.013201-013201
issn 0034-6748
1089-7623
language eng
recordid cdi_proquest_journals_2616104955
source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list); AIP - American Institute of Physics
subjects Adsorption
Degrees of freedom
Hydrogen chloride
Infrared lasers
Molecular beams
Scientific apparatus & instruments
Surface chemistry
Surface dynamics
title A molecular beam-surface apparatus for quantum state-resolved adsorption studies
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T18%3A08%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_scita&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20molecular%20beam-surface%20apparatus%20for%20quantum%20state-resolved%20adsorption%20studies&rft.jtitle=Review%20of%20scientific%20instruments&rft.au=Shen,%20Qiqi&rft.date=2022-01-01&rft.volume=93&rft.issue=1&rft.spage=013201&rft.epage=013201&rft.pages=013201-013201&rft.issn=0034-6748&rft.eissn=1089-7623&rft.coden=RSINAK&rft_id=info:doi/10.1063/5.0049178&rft_dat=%3Cproquest_scita%3E2624950891%3C/proquest_scita%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c383t-8b6add944525c36993e66efa5b6c2b7b4935953e1d9aaf70b7501f2f4c7853fe3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2616104955&rft_id=info:pmid/35104941&rfr_iscdi=true