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Electrosynthesis of a ternary composite film polyaniline-MnO2-graphene in a one-step
In the present work, it has been directly prepared the polyaniline-MnO 2 -grapheneternary composite film onto fluorine-doped tin oxide glass substrate (FTO/PANI-MnO 2 -GR). The film in question were obtained through electropolymerization of aniline with manganese dioxide electrodeposition, both occu...
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Published in: | Ionics 2022, Vol.28 (1), p.317-328 |
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creator | Tounsi, Assia Habelhames, Farid Sayah, Abdelfetteh Bahloul, Ahmed Lamiri, Leila Nessark, Belkacem |
description | In the present work, it has been directly prepared the polyaniline-MnO
2
-grapheneternary composite film onto fluorine-doped tin oxide glass substrate (FTO/PANI-MnO
2
-GR). The film in question were obtained through electropolymerization of aniline with manganese dioxide electrodeposition, both occurring at once under the same imposed potential 1.2 V vs. SCE. The electropolymerization process is first performed with the presence of dispersed graphene (2 mg) in 0.1 M aniline, 25 mM, or 75 mM of manganese sulfate, 0.1 M Na
2
SO
4
, and 1 M H
2
SO
4
electrolyte solution. The carried out work primarily aims to build a new ternary composite film in directly combining mono dimensional coated MnO
2
conducting polyaniline PANI with bi-dimensional graphene sheets. The targeted work is plainly justified by the fact that ternary composites compared to individual components such as supercapacitor electrode materials are endowed with much more high electrochemical capacitance. The process is separately conducted without and with dispersed graphene and its electrolyte solution. The electrochemically synthesized graphene sheets are incorporated under low agitation. The specific capacitance is computed by mean of cyclic voltammetry (CV) technic under 5 m Vs
−1
outcomes 107.29 F g
−1
for FTO/PANI that rises to 249.03 F g
−1
for the ternary composite film FTO/PANI-MnO
2
75-GR. |
doi_str_mv | 10.1007/s11581-021-04316-2 |
format | article |
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2
-grapheneternary composite film onto fluorine-doped tin oxide glass substrate (FTO/PANI-MnO
2
-GR). The film in question were obtained through electropolymerization of aniline with manganese dioxide electrodeposition, both occurring at once under the same imposed potential 1.2 V vs. SCE. The electropolymerization process is first performed with the presence of dispersed graphene (2 mg) in 0.1 M aniline, 25 mM, or 75 mM of manganese sulfate, 0.1 M Na
2
SO
4
, and 1 M H
2
SO
4
electrolyte solution. The carried out work primarily aims to build a new ternary composite film in directly combining mono dimensional coated MnO
2
conducting polyaniline PANI with bi-dimensional graphene sheets. The targeted work is plainly justified by the fact that ternary composites compared to individual components such as supercapacitor electrode materials are endowed with much more high electrochemical capacitance. The process is separately conducted without and with dispersed graphene and its electrolyte solution. The electrochemically synthesized graphene sheets are incorporated under low agitation. The specific capacitance is computed by mean of cyclic voltammetry (CV) technic under 5 m Vs
−1
outcomes 107.29 F g
−1
for FTO/PANI that rises to 249.03 F g
−1
for the ternary composite film FTO/PANI-MnO
2
75-GR.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-021-04316-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aniline ; Capacitance ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Dispersion ; Electrochemistry ; Electrode materials ; Electrolytes ; Energy Storage ; Fluorine ; Glass substrates ; Graphene ; Manganese dioxide ; Optical and Electronic Materials ; Original Paper ; Polyanilines ; Polymerization ; Renewable and Green Energy ; Sheets ; Sulfuric acid ; Tin oxides</subject><ispartof>Ionics, 2022, Vol.28 (1), p.317-328</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-1d67eee1a67f314a2495ee013554128d8cb2e77a46aa25b28ec8cf5d2219b2fd3</citedby><cites>FETCH-LOGICAL-c319t-1d67eee1a67f314a2495ee013554128d8cb2e77a46aa25b28ec8cf5d2219b2fd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Tounsi, Assia</creatorcontrib><creatorcontrib>Habelhames, Farid</creatorcontrib><creatorcontrib>Sayah, Abdelfetteh</creatorcontrib><creatorcontrib>Bahloul, Ahmed</creatorcontrib><creatorcontrib>Lamiri, Leila</creatorcontrib><creatorcontrib>Nessark, Belkacem</creatorcontrib><title>Electrosynthesis of a ternary composite film polyaniline-MnO2-graphene in a one-step</title><title>Ionics</title><addtitle>Ionics</addtitle><description>In the present work, it has been directly prepared the polyaniline-MnO
2
-grapheneternary composite film onto fluorine-doped tin oxide glass substrate (FTO/PANI-MnO
2
-GR). The film in question were obtained through electropolymerization of aniline with manganese dioxide electrodeposition, both occurring at once under the same imposed potential 1.2 V vs. SCE. The electropolymerization process is first performed with the presence of dispersed graphene (2 mg) in 0.1 M aniline, 25 mM, or 75 mM of manganese sulfate, 0.1 M Na
2
SO
4
, and 1 M H
2
SO
4
electrolyte solution. The carried out work primarily aims to build a new ternary composite film in directly combining mono dimensional coated MnO
2
conducting polyaniline PANI with bi-dimensional graphene sheets. The targeted work is plainly justified by the fact that ternary composites compared to individual components such as supercapacitor electrode materials are endowed with much more high electrochemical capacitance. The process is separately conducted without and with dispersed graphene and its electrolyte solution. The electrochemically synthesized graphene sheets are incorporated under low agitation. The specific capacitance is computed by mean of cyclic voltammetry (CV) technic under 5 m Vs
−1
outcomes 107.29 F g
−1
for FTO/PANI that rises to 249.03 F g
−1
for the ternary composite film FTO/PANI-MnO
2
75-GR.</description><subject>Aniline</subject><subject>Capacitance</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Dispersion</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Fluorine</subject><subject>Glass substrates</subject><subject>Graphene</subject><subject>Manganese dioxide</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Polyanilines</subject><subject>Polymerization</subject><subject>Renewable and Green Energy</subject><subject>Sheets</subject><subject>Sulfuric acid</subject><subject>Tin oxides</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kM1OwzAQhC0EEqXwApwicTZ4N4ntHFFVfiRQL-VsucmmTZXawU4PfXsMQeLGYbXSama08zF2C-IehFAPEaDUwAWmKXKQHM_YDLRELpQU52wmqkJxJQp1ya5i3AshJaCasfWyp3oMPp7cuKPYxcy3mc1GCs6GU1b7w-BjN1LWdv0hG3x_sq7rO0f83a2Qb4MdduQo61xy-XSOIw3X7KK1faSb3z1nH0_L9eKFv62eXxePb7zOoRo5NFIREVip2hwKi0VVEgnIy7IA1I2uN0hK2UJai-UGNdW6bssGEaoNtk0-Z3dT7hD855HiaPb-mB7vo0EJstKgRZVUOKnqVDMGas0QukNqZ0CYb3pmomcSPfNDz2Ay5ZMpJrHbUviL_sf1BV1ccoM</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Tounsi, Assia</creator><creator>Habelhames, Farid</creator><creator>Sayah, Abdelfetteh</creator><creator>Bahloul, Ahmed</creator><creator>Lamiri, Leila</creator><creator>Nessark, Belkacem</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2022</creationdate><title>Electrosynthesis of a ternary composite film polyaniline-MnO2-graphene in a one-step</title><author>Tounsi, Assia ; Habelhames, Farid ; Sayah, Abdelfetteh ; Bahloul, Ahmed ; Lamiri, Leila ; Nessark, Belkacem</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-1d67eee1a67f314a2495ee013554128d8cb2e77a46aa25b28ec8cf5d2219b2fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aniline</topic><topic>Capacitance</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Dispersion</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Electrolytes</topic><topic>Energy Storage</topic><topic>Fluorine</topic><topic>Glass substrates</topic><topic>Graphene</topic><topic>Manganese dioxide</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Polyanilines</topic><topic>Polymerization</topic><topic>Renewable and Green Energy</topic><topic>Sheets</topic><topic>Sulfuric acid</topic><topic>Tin oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tounsi, Assia</creatorcontrib><creatorcontrib>Habelhames, Farid</creatorcontrib><creatorcontrib>Sayah, Abdelfetteh</creatorcontrib><creatorcontrib>Bahloul, Ahmed</creatorcontrib><creatorcontrib>Lamiri, Leila</creatorcontrib><creatorcontrib>Nessark, Belkacem</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tounsi, Assia</au><au>Habelhames, Farid</au><au>Sayah, Abdelfetteh</au><au>Bahloul, Ahmed</au><au>Lamiri, Leila</au><au>Nessark, Belkacem</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrosynthesis of a ternary composite film polyaniline-MnO2-graphene in a one-step</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2022</date><risdate>2022</risdate><volume>28</volume><issue>1</issue><spage>317</spage><epage>328</epage><pages>317-328</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>In the present work, it has been directly prepared the polyaniline-MnO
2
-grapheneternary composite film onto fluorine-doped tin oxide glass substrate (FTO/PANI-MnO
2
-GR). The film in question were obtained through electropolymerization of aniline with manganese dioxide electrodeposition, both occurring at once under the same imposed potential 1.2 V vs. SCE. The electropolymerization process is first performed with the presence of dispersed graphene (2 mg) in 0.1 M aniline, 25 mM, or 75 mM of manganese sulfate, 0.1 M Na
2
SO
4
, and 1 M H
2
SO
4
electrolyte solution. The carried out work primarily aims to build a new ternary composite film in directly combining mono dimensional coated MnO
2
conducting polyaniline PANI with bi-dimensional graphene sheets. The targeted work is plainly justified by the fact that ternary composites compared to individual components such as supercapacitor electrode materials are endowed with much more high electrochemical capacitance. The process is separately conducted without and with dispersed graphene and its electrolyte solution. The electrochemically synthesized graphene sheets are incorporated under low agitation. The specific capacitance is computed by mean of cyclic voltammetry (CV) technic under 5 m Vs
−1
outcomes 107.29 F g
−1
for FTO/PANI that rises to 249.03 F g
−1
for the ternary composite film FTO/PANI-MnO
2
75-GR.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-021-04316-2</doi><tpages>12</tpages></addata></record> |
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language | eng |
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subjects | Aniline Capacitance Chemistry Chemistry and Materials Science Condensed Matter Physics Dispersion Electrochemistry Electrode materials Electrolytes Energy Storage Fluorine Glass substrates Graphene Manganese dioxide Optical and Electronic Materials Original Paper Polyanilines Polymerization Renewable and Green Energy Sheets Sulfuric acid Tin oxides |
title | Electrosynthesis of a ternary composite film polyaniline-MnO2-graphene in a one-step |
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