Properties Investigation of Epoxidized Sunflower Oil as Bioplasticizer for Poly (Lactic Acid)

• Published in: Journal of polymers and the environment 2022, Vol.30 (1), p.232-245
• Main Authors: Bouti, Mohamed, Irinislimane, Ratiba, Belhaneche-Bensemra, Naima
• Format: Article
• Language: English
• Subjects: Biodegradability; Biodegradable materials; Biodegradation; Calorimetry; Chain mobility; Chemistry; Chemistry and Materials Science; Differential scanning calorimetry; Ductility; Elongation; Environmental Chemistry; Environmental Engineering/Biotechnology; Glass transition temperature; Helianthus; Industrial Chemistry/Chemical Engineering; Light microscopy; Materials Science; Melt temperature; Modulus of elasticity; Morphology; Optical microscopy; Optical properties; Original Paper; Plasticizers; Polylactic acid; Polymer Sciences; Scanning electron microscopy; Soybeans; Sunflower oil; Sunflowers; Tensile strength; Thermal properties; Thermal stability; Thermodynamic properties; Thermogravimetric analysis; Transition temperatures; Vegetable oils
• ISSN: 1566-2543; 1572-8919
• DOI: 10.1007/s10924-021-02194-3

This study aims to improve low intrinsic ductility of poly (lactic acid) (PLA) by using a novel bio-sourced plasticizer environmentally friendly and cost-effective and to get a fully biodegradable material with potential application in films manufacturing. For that purpose, commercial sunflower oil (SO) was epoxidized and epoxidized sunflower oil (ESO) was used as plasticizer for PLA. To investigate ESO potential as plasticizer for PLA, its plasticizing effect was compared with commercial epoxidized soya bean oil (ESBO). Bioblends based on PLA and epoxidized vegetable oils (EVO) as bioplasticizers were prepared. The plasticizers (ESO or ESBO) were respectively compounded with PLA at 10, 20, 30, and 40 wt%. Mechanical (tensile and Shore D hardness), thermal (differential scanning calorimetry (DSC), thermogravimetric analysis (TGA)) and morphological properties (optical microscopy and scanning electron microscopy (SEM)) were characterized. The results showed that the addition of ESO or ESBO to PLA decreased tensile strength and tensile modulus compared to neat PLA but increased elongation at break for which an optimum (9 %, 16 and 34 % for ESBO, ESO 5.5 % and ESO 6.5 % respectively) was reached at a content of 20 wt% of plasticizer. The structures of the obtained plasticized PLA were confirmed by FTIR spectroscopy. The thermal properties (DSC), such as glass transition temperature (T g ) and melting temperature (T m ) were slightly decreased by addition of plasticizer into PLA, indicating that plasticizer increases the chain mobility and SEM analysis proved successful modification on the PLA brittle morphology with addition of EVO. On the other hand, TGA results revealed increase in the thermal stability. Also the results showed the effect of the EVO weight and the epoxy content (O.O value) on the improvement of the properties of PLA. ESO 6.5 % at 20wt% was an efficient plasticizer for PLA.