Comparative Study on UV-AOPs for Efficient Continuous Flow Removal of 4-tert-Butylphenol

In the present study, UV-light-driven advanced oxidation processes (AOPs) have been employed for the degradation of 4-tert-Butylphenol (4-t-BP) in water under continuous flow conditions. The effects of varying space time (10, 20, 40, 60 and 120 min) and oxidant dosage (88.3 mg/L, 176.6 mg/L and 264...

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Bibliographic Details
Published in:Processes 2022-01, Vol.10 (1), p.8
Main Authors: Mergenbayeva, Saule, Poulopoulos, Stavros G.
Format: Article
Language:English
Subjects:
Aqueous solutions
Biodegradation
By products
Carbon
Comparative studies
Continuous flow
Degradation
Efficiency
Experiments
Hydrogen peroxide
Iron
Light
Mineralization
Organic carbon
Oxidants
Oxidation
Oxidizing agents
Photocatalysis
Pollutants
Titanium dioxide
Total organic carbon
Ultraviolet radiation
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Summary:In the present study, UV-light-driven advanced oxidation processes (AOPs) have been employed for the degradation of 4-tert-Butylphenol (4-t-BP) in water under continuous flow conditions. The effects of varying space time (10, 20, 40, 60 and 120 min) and oxidant dosage (88.3 mg/L, 176.6 mg/L and 264 mg/L) were examined. 4-t-BP degradation efficiency in the UV-induced AOPs followed the order of UV/H2O2 (264.9 mg/L) ≈ UV/Fe2+/H2O2 > UV/Fe3+/H2O2 > UV/H2O2 (176.6 mg/L) > UV/H2O2 (88.3 mg/L) > UV/Fe-TiO2 > UV/TiO2 > UV, while UV/Fe3+/H2O2 was the most efficient process in terms of Total Organic Carbon (TOC) removal (at the space time of 60 min) among those tested. The combination of UV with 88.3 mg/L H2O2 enhanced pollutant removal from 51.29% to 93.34% after 10 min of irradiation. The presence of H2O2 contributed to the highest 4-t-BP and TOC removal values. Interestingly, the increase in space time from 20 to 60 min resulted in surpassing of the activity of the Fe-TiO2 over commercial TiO2, although it had an almost negligible positive impact on the performance of the UV/H2O2 system as well as H2O2 concentration. The results obtained showed that more than 80% of 4-t-BP could be successfully degraded by both heterogeneous and homogeneous AOPs after 60 min.
ISSN:2227-9717
2227-9717
DOI:10.3390/pr10010008