Effects of trace Si impurities in water on the growth of calcite nanoparticles

• Published in: CrystEngComm 2022-01, Vol.24 (4), p.747-754
• Main Authors: Kezuka, Yuki, Murata, Hidenobu, Yoshida, Maya, Eguchi, Kenichiro, Nakahira, Atsushi, Tajika, Masahiko
• Format: Article
• Language: English
• Subjects: Amorphous materials; Calcite; High temperature; Impurities; Morphology; Nanocrystals; Nanoparticles; Silicon dioxide; Slaked lime; Slurries
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/d1ce01463c

Effects of trace inorganic Si impurities in water on the growth of calcite nanocrystals are evaluated using high-purity Ca(OH) 2 and amorphous SiO 2 as the starting materials. First, pristine calcite spheroidal particles (∼40 nm) are synthesized by CO 2 bubbling into Ca(OH) 2 aqueous slurry. Next, slurries of calcite particles with several different Si-coexisting concentrations were prepared and incubated at 95 °C to induce the calcite growth. Particle morphology before and after the slurry incubation were investigated, and growth inhibition with increasing Si concentrations was clearly observed. Amorphous SiO 2 , which is hydrolysed into orthosilicic acid (Si(OH) 4 ) in water at elevated temperatures, is found to act as a proton buffer, and prevent the formation of the alkaline environment required for calcite growth. Si-coexisting effects demonstrated in this study are important for understanding the calcite mineralization process and particle morphology control. Si impurities act as proton buffers in water and prevent the formation of the alkaline environment required for calcite growth.