Loading…
Size effect of the carbon-supported bimetallic Fe-Co nanoparticles on the catalytic activity in the Fischer-Tropsch synthesis
[Display omitted] •Fe-Co nanoparticles of 5–14 nm supported on chitosan-derived carbon were prepared.•FTS was conducted without pre-reduction of the catalysts.•10 nm Fe-Co nanoalloys showed a high specific activity (126 μmolCO/(gFe-Co·s)).•FTS activity and selectivity strongly depend on the Fe-Co na...
Saved in:
| Published in: | Fuel (Guildford) 2022-02, Vol.310, p.122455, Article 122455 |
|---|---|
| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c328t-99fd5013a1cd2e8e8246d8049f52c46520a96adf0314f6458f4c825245018803 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c328t-99fd5013a1cd2e8e8246d8049f52c46520a96adf0314f6458f4c825245018803 |
| container_end_page | |
| container_issue | |
| container_start_page | 122455 |
| container_title | Fuel (Guildford) |
| container_volume | 310 |
| creator | Vasilev, Andrey A. Ivantsov, Mikhail I. Dzidziguri, Ella L. Efimov, Mikhail N. Muratov, Dmitry G. Kulikova, Maya V. Zhilyaeva, Natalia A. Karpacheva, Galina P. |
| description | [Display omitted]
•Fe-Co nanoparticles of 5–14 nm supported on chitosan-derived carbon were prepared.•FTS was conducted without pre-reduction of the catalysts.•10 nm Fe-Co nanoalloys showed a high specific activity (126 μmolCO/(gFe-Co·s)).•FTS activity and selectivity strongly depend on the Fe-Co nanoparticle size.
Carbon-supported bimetallic Fe-Co nanocatalysts with different particle sizes have been synthesized by one-pot method involving simultaneous metal nanoparticles formation and chitosan carbonization. The Fe-Co particle size has been found to vary from 5 to 14 nm depending on the amount of metal loaded in the polymer precursor. For the first time, the size effect of Fe-Co alloy nanoparticles on the specific catalyst activity, yield and selectivity of the products of the Fischer-Tropsch synthesis has been studied. It has been revealed that smaller size of the Fe-Co nanoparticles allows to achieve the maximum selectivity towards C5+ hydrocarbons at lower reaction temperature. The catalyst with the Fe-Co average particle size of 10 nm has been demonstrated the highest specific activity (per unit mass) of 126 μmolCO/(gFe-Co·s). The structure of the Fe-Co bimetallic nanoparticles formed in the composites with different initial metal loading was studied and reviewed for details by XRD analysis. |
| doi_str_mv | 10.1016/j.fuel.2021.122455 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2625331426</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0016236121023267</els_id><sourcerecordid>2625331426</sourcerecordid><originalsourceid>FETCH-LOGICAL-c328t-99fd5013a1cd2e8e8246d8049f52c46520a96adf0314f6458f4c825245018803</originalsourceid><addsrcrecordid>eNp9kEFLwzAYhoMoOKd_wFPAc2uSNl0KXmQ4FQYe3D1k6ReW0jU1SQcV_O9m1LOnhDfvk-_jQeiekpwSWj22uRmhyxlhNKeMlZxfoAUVqyJbUV5cogVJrYwVFb1GNyG0hJCV4OUC_Xzab8BgDOiIncHxAFgrv3d9FsZhcD5Cg_f2CFF1ndV4A9na4V71blA-Wt1BwK7_w1JnShlWOtqTjRO288vGBn0An-28G9INh6lPcbDhFl0Z1QW4-zuXaLd52a3fsu3H6_v6eZvpgomY1bVpOKGForphIECwsmoEKWvDmS4rzoiqK9UYUtDSVCUXptSC8aSBUCFIsUQP87eDd18jhChbN_o-TZSsYrxIGKtSi80t7V0IHowcvD0qP0lK5NmybOXZsjxblrPlBD3NEKT1Txa8DNpCr6GxPimVjbP_4b99xIY3</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2625331426</pqid></control><display><type>article</type><title>Size effect of the carbon-supported bimetallic Fe-Co nanoparticles on the catalytic activity in the Fischer-Tropsch synthesis</title><source>ScienceDirect Journals</source><creator>Vasilev, Andrey A. ; Ivantsov, Mikhail I. ; Dzidziguri, Ella L. ; Efimov, Mikhail N. ; Muratov, Dmitry G. ; Kulikova, Maya V. ; Zhilyaeva, Natalia A. ; Karpacheva, Galina P.</creator><creatorcontrib>Vasilev, Andrey A. ; Ivantsov, Mikhail I. ; Dzidziguri, Ella L. ; Efimov, Mikhail N. ; Muratov, Dmitry G. ; Kulikova, Maya V. ; Zhilyaeva, Natalia A. ; Karpacheva, Galina P.</creatorcontrib><description>[Display omitted]
•Fe-Co nanoparticles of 5–14 nm supported on chitosan-derived carbon were prepared.•FTS was conducted without pre-reduction of the catalysts.•10 nm Fe-Co nanoalloys showed a high specific activity (126 μmolCO/(gFe-Co·s)).•FTS activity and selectivity strongly depend on the Fe-Co nanoparticle size.
Carbon-supported bimetallic Fe-Co nanocatalysts with different particle sizes have been synthesized by one-pot method involving simultaneous metal nanoparticles formation and chitosan carbonization. The Fe-Co particle size has been found to vary from 5 to 14 nm depending on the amount of metal loaded in the polymer precursor. For the first time, the size effect of Fe-Co alloy nanoparticles on the specific catalyst activity, yield and selectivity of the products of the Fischer-Tropsch synthesis has been studied. It has been revealed that smaller size of the Fe-Co nanoparticles allows to achieve the maximum selectivity towards C5+ hydrocarbons at lower reaction temperature. The catalyst with the Fe-Co average particle size of 10 nm has been demonstrated the highest specific activity (per unit mass) of 126 μmolCO/(gFe-Co·s). The structure of the Fe-Co bimetallic nanoparticles formed in the composites with different initial metal loading was studied and reviewed for details by XRD analysis.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2021.122455</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Bimetals ; Carbon ; Catalysts ; Catalytic activity ; Chemical synthesis ; Chitosan ; Cobalt ; Fe-Co solid solution ; Ferrous alloys ; Fischer-Tropsch process ; Fischer-Tropsch synthesis ; Iron ; Metal–carbon nanocomposites ; Nanoalloys ; Nanoparticles ; Particle size ; Polymers ; Prepolymers ; Selectivity ; Size effects</subject><ispartof>Fuel (Guildford), 2022-02, Vol.310, p.122455, Article 122455</ispartof><rights>2021 Elsevier Ltd</rights><rights>Copyright Elsevier BV Feb 15, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-99fd5013a1cd2e8e8246d8049f52c46520a96adf0314f6458f4c825245018803</citedby><cites>FETCH-LOGICAL-c328t-99fd5013a1cd2e8e8246d8049f52c46520a96adf0314f6458f4c825245018803</cites><orcidid>0000-0001-7996-474X ; 0000-0003-3226-9584</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Vasilev, Andrey A.</creatorcontrib><creatorcontrib>Ivantsov, Mikhail I.</creatorcontrib><creatorcontrib>Dzidziguri, Ella L.</creatorcontrib><creatorcontrib>Efimov, Mikhail N.</creatorcontrib><creatorcontrib>Muratov, Dmitry G.</creatorcontrib><creatorcontrib>Kulikova, Maya V.</creatorcontrib><creatorcontrib>Zhilyaeva, Natalia A.</creatorcontrib><creatorcontrib>Karpacheva, Galina P.</creatorcontrib><title>Size effect of the carbon-supported bimetallic Fe-Co nanoparticles on the catalytic activity in the Fischer-Tropsch synthesis</title><title>Fuel (Guildford)</title><description>[Display omitted]
•Fe-Co nanoparticles of 5–14 nm supported on chitosan-derived carbon were prepared.•FTS was conducted without pre-reduction of the catalysts.•10 nm Fe-Co nanoalloys showed a high specific activity (126 μmolCO/(gFe-Co·s)).•FTS activity and selectivity strongly depend on the Fe-Co nanoparticle size.
Carbon-supported bimetallic Fe-Co nanocatalysts with different particle sizes have been synthesized by one-pot method involving simultaneous metal nanoparticles formation and chitosan carbonization. The Fe-Co particle size has been found to vary from 5 to 14 nm depending on the amount of metal loaded in the polymer precursor. For the first time, the size effect of Fe-Co alloy nanoparticles on the specific catalyst activity, yield and selectivity of the products of the Fischer-Tropsch synthesis has been studied. It has been revealed that smaller size of the Fe-Co nanoparticles allows to achieve the maximum selectivity towards C5+ hydrocarbons at lower reaction temperature. The catalyst with the Fe-Co average particle size of 10 nm has been demonstrated the highest specific activity (per unit mass) of 126 μmolCO/(gFe-Co·s). The structure of the Fe-Co bimetallic nanoparticles formed in the composites with different initial metal loading was studied and reviewed for details by XRD analysis.</description><subject>Bimetals</subject><subject>Carbon</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical synthesis</subject><subject>Chitosan</subject><subject>Cobalt</subject><subject>Fe-Co solid solution</subject><subject>Ferrous alloys</subject><subject>Fischer-Tropsch process</subject><subject>Fischer-Tropsch synthesis</subject><subject>Iron</subject><subject>Metal–carbon nanocomposites</subject><subject>Nanoalloys</subject><subject>Nanoparticles</subject><subject>Particle size</subject><subject>Polymers</subject><subject>Prepolymers</subject><subject>Selectivity</subject><subject>Size effects</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLwzAYhoMoOKd_wFPAc2uSNl0KXmQ4FQYe3D1k6ReW0jU1SQcV_O9m1LOnhDfvk-_jQeiekpwSWj22uRmhyxlhNKeMlZxfoAUVqyJbUV5cogVJrYwVFb1GNyG0hJCV4OUC_Xzab8BgDOiIncHxAFgrv3d9FsZhcD5Cg_f2CFF1ndV4A9na4V71blA-Wt1BwK7_w1JnShlWOtqTjRO288vGBn0An-28G9INh6lPcbDhFl0Z1QW4-zuXaLd52a3fsu3H6_v6eZvpgomY1bVpOKGForphIECwsmoEKWvDmS4rzoiqK9UYUtDSVCUXptSC8aSBUCFIsUQP87eDd18jhChbN_o-TZSsYrxIGKtSi80t7V0IHowcvD0qP0lK5NmybOXZsjxblrPlBD3NEKT1Txa8DNpCr6GxPimVjbP_4b99xIY3</recordid><startdate>20220215</startdate><enddate>20220215</enddate><creator>Vasilev, Andrey A.</creator><creator>Ivantsov, Mikhail I.</creator><creator>Dzidziguri, Ella L.</creator><creator>Efimov, Mikhail N.</creator><creator>Muratov, Dmitry G.</creator><creator>Kulikova, Maya V.</creator><creator>Zhilyaeva, Natalia A.</creator><creator>Karpacheva, Galina P.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0001-7996-474X</orcidid><orcidid>https://orcid.org/0000-0003-3226-9584</orcidid></search><sort><creationdate>20220215</creationdate><title>Size effect of the carbon-supported bimetallic Fe-Co nanoparticles on the catalytic activity in the Fischer-Tropsch synthesis</title><author>Vasilev, Andrey A. ; Ivantsov, Mikhail I. ; Dzidziguri, Ella L. ; Efimov, Mikhail N. ; Muratov, Dmitry G. ; Kulikova, Maya V. ; Zhilyaeva, Natalia A. ; Karpacheva, Galina P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-99fd5013a1cd2e8e8246d8049f52c46520a96adf0314f6458f4c825245018803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Bimetals</topic><topic>Carbon</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical synthesis</topic><topic>Chitosan</topic><topic>Cobalt</topic><topic>Fe-Co solid solution</topic><topic>Ferrous alloys</topic><topic>Fischer-Tropsch process</topic><topic>Fischer-Tropsch synthesis</topic><topic>Iron</topic><topic>Metal–carbon nanocomposites</topic><topic>Nanoalloys</topic><topic>Nanoparticles</topic><topic>Particle size</topic><topic>Polymers</topic><topic>Prepolymers</topic><topic>Selectivity</topic><topic>Size effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vasilev, Andrey A.</creatorcontrib><creatorcontrib>Ivantsov, Mikhail I.</creatorcontrib><creatorcontrib>Dzidziguri, Ella L.</creatorcontrib><creatorcontrib>Efimov, Mikhail N.</creatorcontrib><creatorcontrib>Muratov, Dmitry G.</creatorcontrib><creatorcontrib>Kulikova, Maya V.</creatorcontrib><creatorcontrib>Zhilyaeva, Natalia A.</creatorcontrib><creatorcontrib>Karpacheva, Galina P.</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vasilev, Andrey A.</au><au>Ivantsov, Mikhail I.</au><au>Dzidziguri, Ella L.</au><au>Efimov, Mikhail N.</au><au>Muratov, Dmitry G.</au><au>Kulikova, Maya V.</au><au>Zhilyaeva, Natalia A.</au><au>Karpacheva, Galina P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Size effect of the carbon-supported bimetallic Fe-Co nanoparticles on the catalytic activity in the Fischer-Tropsch synthesis</atitle><jtitle>Fuel (Guildford)</jtitle><date>2022-02-15</date><risdate>2022</risdate><volume>310</volume><spage>122455</spage><pages>122455-</pages><artnum>122455</artnum><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>[Display omitted]
•Fe-Co nanoparticles of 5–14 nm supported on chitosan-derived carbon were prepared.•FTS was conducted without pre-reduction of the catalysts.•10 nm Fe-Co nanoalloys showed a high specific activity (126 μmolCO/(gFe-Co·s)).•FTS activity and selectivity strongly depend on the Fe-Co nanoparticle size.
Carbon-supported bimetallic Fe-Co nanocatalysts with different particle sizes have been synthesized by one-pot method involving simultaneous metal nanoparticles formation and chitosan carbonization. The Fe-Co particle size has been found to vary from 5 to 14 nm depending on the amount of metal loaded in the polymer precursor. For the first time, the size effect of Fe-Co alloy nanoparticles on the specific catalyst activity, yield and selectivity of the products of the Fischer-Tropsch synthesis has been studied. It has been revealed that smaller size of the Fe-Co nanoparticles allows to achieve the maximum selectivity towards C5+ hydrocarbons at lower reaction temperature. The catalyst with the Fe-Co average particle size of 10 nm has been demonstrated the highest specific activity (per unit mass) of 126 μmolCO/(gFe-Co·s). The structure of the Fe-Co bimetallic nanoparticles formed in the composites with different initial metal loading was studied and reviewed for details by XRD analysis.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2021.122455</doi><orcidid>https://orcid.org/0000-0001-7996-474X</orcidid><orcidid>https://orcid.org/0000-0003-3226-9584</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0016-2361 |
| ispartof | Fuel (Guildford), 2022-02, Vol.310, p.122455, Article 122455 |
| issn | 0016-2361 1873-7153 |
| language | eng |
| recordid | cdi_proquest_journals_2625331426 |
| source | ScienceDirect Journals |
| subjects | Bimetals Carbon Catalysts Catalytic activity Chemical synthesis Chitosan Cobalt Fe-Co solid solution Ferrous alloys Fischer-Tropsch process Fischer-Tropsch synthesis Iron Metal–carbon nanocomposites Nanoalloys Nanoparticles Particle size Polymers Prepolymers Selectivity Size effects |
| title | Size effect of the carbon-supported bimetallic Fe-Co nanoparticles on the catalytic activity in the Fischer-Tropsch synthesis |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-02T04%3A47%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Size%20effect%20of%20the%20carbon-supported%20bimetallic%20Fe-Co%20nanoparticles%20on%20the%20catalytic%20activity%20in%20the%20Fischer-Tropsch%20synthesis&rft.jtitle=Fuel%20(Guildford)&rft.au=Vasilev,%20Andrey%20A.&rft.date=2022-02-15&rft.volume=310&rft.spage=122455&rft.pages=122455-&rft.artnum=122455&rft.issn=0016-2361&rft.eissn=1873-7153&rft_id=info:doi/10.1016/j.fuel.2021.122455&rft_dat=%3Cproquest_cross%3E2625331426%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c328t-99fd5013a1cd2e8e8246d8049f52c46520a96adf0314f6458f4c825245018803%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2625331426&rft_id=info:pmid/&rfr_iscdi=true |