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Wafer‐Scale Graphene Anodes Replace Indium Tin Oxide in Organic Light‐Emitting Diodes

Indium tin oxide (ITO) is widely used for transparent electrode applications due to its high electrical conductivity and relatively straightforward deposition technology. However, there are long standing concerns for its use due to the limited availability of indium in the Earth's crust. Graphe...

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Bibliographic Details
Published in:Advanced optical materials 2022-02, Vol.10 (3), p.n/a
Main Authors: Weng, Zhichao, Dixon, Sebastian C., Lee, Lok Yi, Humphreys, Colin J., Guiney, Ivor, Fenwick, Oliver, Gillin, William P.
Format: Article
Language:English
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Summary:Indium tin oxide (ITO) is widely used for transparent electrode applications due to its high electrical conductivity and relatively straightforward deposition technology. However, there are long standing concerns for its use due to the limited availability of indium in the Earth's crust. Graphene is considered as a promising material for replacing ITO but for this to become possible, a low‐cost and scalable fabrication method that produces graphene with comparable performance to ITO is required. By taking advantage of high‐quality monolayer graphene directly deposited on a transparent substrate using a commercially available metal–organic chemical vapor deposition (MOCVD) system, graphene‐based organic light‐emitting diodes (OLEDs) without the use of metal catalysts or a graphene transfer process are developed. The as‐grown graphene is patterned using photolithography and its conductivity is enhanced by doping with nitric acid prior to deposition of the OLED stack. The electrical and optical performances of the as‐fabricated graphene‐based OLEDs are identical to the control devices with conventional ITO anodes. All the processes used in the fabrication of graphene‐based OLEDs can be performed at wafer scale. This paper demonstrates the potential for graphene to replace ITO as anodes in OLED devices in a technologically and commercially effective manner. Indium is one of the nine rarest elements in the Earth's crust. In this paper, graphene is used to replace indium tin oxide (ITO) in manufactured opto‐electronic devices. Large‐area, catalyst‐ and transfer‐free graphene is produced in a metal–organic chemical vapor deposition reactor. A graphene‐organic light‐emitting diode (OLED) with identical properties to an ITO‐OLED is fabricated.
ISSN:2195-1071
2195-1071
DOI:10.1002/adom.202101675