Measurement report: Long-term variations in surface NOx and SO2 mixing ratios from 2006 to 2016 at a background site in the Yangtze River Delta region, China

• Published in: Atmospheric chemistry and physics 2022-01, Vol.22 (2), p.1015-1033
• Main Authors: Yin, Qingqing, Ma, Qianli, Lin, Weili, Xu, Xiaobin, Yao, Jie
• Format: Article
• Language: English
• Subjects: Air pollution; Air quality; Annual; Diurnal variations; Emissions; Emissions control; Environmental policy; Gases; Haze; Humidity; Industrial emissions; Long-term changes; Meteorological conditions; Mixing ratio; Nitrogen compounds; Nitrogen oxides; Particulates; Pollutants; Quality control; Rivers; Satellite observation; Seasonal variation; Seasonal variations; Sulfur dioxide; Trends; Urban areas; Vehicle emissions; Wind
• ISSN: 1680-7316; 1680-7324
• DOI: 10.5194/acp-22-1015-2022

China has been experiencing rapid changes in emissions of air pollutants in recent decades. Increased emissions of primary particulates and reactive gases caused severe haze in several polluted regions including the Yangtze River Delta (YRD). Measures implemented in recent years for improving air quality have reduced the emissions of NOx, SO2, etc. The emission changes in these gases are reflected by tropospheric columns from satellite observations and surface measurements of surface concentrations from urban sites. However, little is known about the long-term variations in regional background NOx and SO2. In this study, we present NOx and SO2 measurements from the Lin'an station (LAN; 30∘18' N, 119∘44′ E; 138.6 m a.s.l.), one of the Global Atmosphere Watch (GAW) stations in China. We characterize the seasonal and diurnal variations and study the long-term trends of NOx and SO2 mixing ratios observed at LAN from 2006 to 2016. We also interpret the observed variations and trends in terms of changes in meteorological conditions as well as emission of these gases. The overall average mixing ratios of NOx (NO2) and SO2 during 2006–2016 were 13.6 ± 1.2 ppb (12.5 ± 4.6) and 7.0 ± 4.2 ppb, respectively. The averaged seasonal variations showed maximum values of NOx and SO2 in December (23.5 ± 4.4 ppb) and January (11.9 ± 6.2 ppb), respectively, and minimum values of 7.1 ± 0.8 and 2.8 ± 2.3 ppb (both in July), respectively. The average diurnal variation characteristics of NOx and SO2 differed considerably from each other, though the daily average mixing ratios of both gases were significantly correlated (R2=0.29, P