Electrochemical Oxidative Sulfonylation of N‐Arylamides/Amine with Sodium Sulfinates

A mild and efficient protocol for sulfonylation of 8‐aminoquinolines, naphthylamides and anilides with sodium sulfinates by anodic oxidation at room temperature was developed. In the absence of any additional catalyst and oxidant, a series of sulfonylated products were achieved in good to excellent...

Full description

Saved in:
Bibliographic Details
Published in:Asian journal of organic chemistry 2022-02, Vol.11 (2), p.n/a
Main Authors: Yu, Yingliang, Fang, Yang, Tang, Rumeng, Xu, Dongping, Dai, Shuaishuai, Zhang, W.
Format: Article
Language:English
Subjects:
amine
Aminoquinolines
Anodizing
electrocatalysis
Functional groups
N-arylamides
Organic chemistry
Oxidation
Oxidizing agents
Room temperature
Selectivity
Sodium
sodium sulfinates
sulfonylation
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A mild and efficient protocol for sulfonylation of 8‐aminoquinolines, naphthylamides and anilides with sodium sulfinates by anodic oxidation at room temperature was developed. In the absence of any additional catalyst and oxidant, a series of sulfonylated products were achieved in good to excellent yields. This proposal features good water tolerance, excellent selectivity and broad functional group compatibility. An efficient protocol for sulfonylation of N‐arylamides/amine with sulfinate salts has been developed via anodic oxidation at room temperature in an undivided cell.
ISSN:2193-5807
2193-5815
DOI:10.1002/ajoc.202100805