Integration of natural clay into cellulose membrane for efficient CO2/N2 separation

It is important to design gas separation membrane from natural resources such as clay and cellulose. In this work, natural clay attapulgite (ATP) nanorods were integrated into cellulose nanofibers (CNFs) to fabricate organic/inorganic composite membranes. The microporous ATP nanorods were well-dispe...

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Bibliographic Details
Published in:Cellulose (London) 2022-02, Vol.29 (3), p.1873-1881
Main Authors: Wang, Zhongguo, Li, Mengjie, Zhang, Xiong-Fei, Zhou, Yichen, Yao, Jianfeng
Format: Article
Language:English
Subjects:
Bioorganic Chemistry
Carbon dioxide
Cellulose
Cellulose fibers
Ceramics
Chemistry
Chemistry and Materials Science
Clay
Composites
Gas separation
Glass
Membranes
Nanofibers
Nanorods
Natural gas
Natural Materials
Natural resources
Organic Chemistry
Original Research
Physical Chemistry
Polymer Sciences
Selectivity
Sustainable Development
Vacuum filtration
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Summary:It is important to design gas separation membrane from natural resources such as clay and cellulose. In this work, natural clay attapulgite (ATP) nanorods were integrated into cellulose nanofibers (CNFs) to fabricate organic/inorganic composite membranes. The microporous ATP nanorods were well-dispersed in the CNF suspension owing to the sufficient electrostatic repulsion. The ATP@CNF thin layer was deposited on the porous Nylon support via a simple vacuum filtration process. Such prepared ATP@CNF membranes were effective for CO 2 /N 2 separation as the non-selective interfacial voids/defects formed by ATP nanorods were successfully sealed by the flexible CNF chains. With an ATP loading of ca. 50.0 wt%, the optimal AC-2 membrane presented a CO 2 permeability of 65.5 Barrer with a CO 2 /N 2 ideal selectivity of 43.7. The separation mechanism was mainly attributed to the molecular-sieving ability of porous ATP nanorods and gas barrier property of CNFs. This study provided a novel route for the design of all-natural separation membranes by interfacial engineering routes.
ISSN:0969-0239
1572-882X
DOI:10.1007/s10570-021-04407-3