High performance sky-blue perovskite light-emitting diodes enabled by a bifunctional phosphate molecule

• Published in: Journal of alloys and compounds 2022-03, Vol.897, p.162727, Article 162727
• Main Authors: Zhang, Yong-Wen, Liang, Jia-Ming, Diao, Zheng-Liang, Chen, Ji-Yang, Tan, Wan-Yi, Qian, Yan-Nan, Xiao, Lian-Gang, Min, Yonggang
• Format: Article
• Language: English
• Subjects: Blue emission; Charge transport; Defects; Ethane; Excitons; Lead; Leakage current; Light emitting diodes; Moisture resistance; Passivity; Perovskite light emitting diodes; Perovskites; Phosphine oxide groups; Quantum efficiency; Radiative recombination
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2021.162727

Defects such as uncoordinated lead ions and surface charged defects are still one of critical issues for perovskite light-emitting diodes (PeLEDs). The presence of these defects can trap excitons, resulting in enhanced nonradiative recombination and thus poor efficiencies of PeLEDs. Defect passivation via passivation agents is an effective way to solve this issue. In this work, we introduce a bifunctional phosphate molecule 6,6′-(ethane-1,2-diyl)bis(dibenzo[c,e][1,2]oxaphosphinine 6-oxide) (DIDOPO) as a passivation agent into the perovskite, where DIDOPO can bind with the perovskite via the chemical interaction between the PO groups and uncoordinated Pb ions. Thus, the incorporation of DIDOPO effectively passivates the defects, leading to improved radiative recombination. Simultaneously, the as-prepared perovskite film produces dense and smooth morphology, which is favorable to good contact with the adjacent charge transport layers and the reduction of leakage current. As a result, the sky-blue PeLEDs modified by DIDOPO show improved efficiency with the maximum external quantum efficiency (EQEmax) of 5.52% and the average EQEmax of 5.09%. Furthermore, attributed to the alkyl chain as the bridge between the phosphate groups, DIDOPO accumulated at the perovskite surface is able to decrease hydrophilic behavior of the perovskite. The PeLEDs containing DIDOPO possess enhanced moisture resistance, remaining ca. 91–92% of the initial EQE after storage for 120 h in ambient atmosphere with the humidity of ca. 40%. Introduce a bifunctional phosphate molecule DIDOPO that has an alkyl chain as the bridge between the phosphate groups for the perovskite to improve the effieciency and simultaneously the environmental stability of the sky-blue perovskite light-emitting diode. [Display omitted] •DIDOPO binds with the perovskite via the chemical interaction between PO and uncoordinated Pb.•DIDOPO effectively passivates the defects and suppresses nonradiative recombination.•The sky-blue PeLEDs show EQEmax of 5.52% with the average EQEmax of 5.09%.•DIDOPO accumulated at the perovskite surface helps yield more hydrophobic perovskite.•The perovskite containing DIDOPO possesses enhanced moisture resistance.