Sequential and/or Simultaneous Wet-Impregnation Impact on the Mesoporous Pt/Sn/Zn/γ-Al2O3 Catalysts for the Direct Ethane Dehydrogenation

This study is aimed at investigating the impact of catalyst preparation’s approach (either sequential and/or simultaneous wet impregnation) to a mesoporous series of Pt/A, Sn/A, PtSn/A, SnPt/A, (PtSn)/A, (PtSn)Zn/A, and (PtSnZn)/A catalysts for direct ethane dehydrogenation. The (PtSn)/A and (PtSnZn...

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Bibliographic Details
Published in:Journal of nanomaterials 2022-02, Vol.2022
Main Authors: Ali, Arshid M., Zahrani, Abdulrahim A., Daous, Muhammad A., Podila, Seetharamulu, Alshehri, Majid Khalid, Rather, Sami-ullah, Saeed, Usman
Format: Article
Language:English
Subjects:
Aluminum oxide
Catalysts
Catalytic activity
Chloride
Cleavage
Dehydrogenation
Ethane
Ethylene
Fluidized bed reactors
Hydrogen bonds
Impregnation
Intermetallic compounds
Nanomaterials
Platinum
Temperature
Transitional aluminas
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Summary:This study is aimed at investigating the impact of catalyst preparation’s approach (either sequential and/or simultaneous wet impregnation) to a mesoporous series of Pt/A, Sn/A, PtSn/A, SnPt/A, (PtSn)/A, (PtSn)Zn/A, and (PtSnZn)/A catalysts for direct ethane dehydrogenation. The (PtSn)/A and (PtSnZn)/A had shown both higher initial specific activity (s-1) and reaction rate constant Kd (h-1) (13063.86 (s-1) and 12489.69 (s-1) and 0.09 (h-1) and 0.06 (h-1)), respectively. The catalyst preparation approach had direct impact to the availability and dispersion of mesoporous particles of either active metal and/or promoter that influences either to hinder the C-C cleavage and/or to promote C-H bond cleavage in the dehydrogenation of ethane to ethene. The active metal component was present in the form of Pt, Pt+2, Al+3, Sn+4, and Zn+2 states. The enhanced catalytic activity is attributed to the Pt4Sn and PtZn formed phases in addition to highly dispersed mesoporous Pt particles. Based on the obtained results, the catalysts prepared by using simultaneous wet impregnation had shown higher catalytic activity and catalyst stability as to that of sequential wet impregnation.
ISSN:1687-4110
1687-4129
DOI:10.1155/2022/8739993