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Synthesis, Temperature Behavior, and Hydrolytic Stability of Na–Zr and Ca–Zr Phosphate Molybdates and Phosphate Tungstates
— We have synthesized Na 1 – x Zr 2 (PO 4 ) 3 – x (ХO 4 ) x and Сa 0.5 – x Zr 2 (PO 4 ) 3 – x (ХO 4 ) x (X = Mo, W; 0 ≤ x ≤ 0.5) compounds with the NZP structure. Their thermal expansion has been studied in the temperature range 25–800°C using high-temperature X-ray diffraction and shown to have a...
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| Published in: | Inorganic materials 2022, Vol.58 (1), p.78-89 |
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| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 89 |
| container_issue | 1 |
| container_start_page | 78 |
| container_title | Inorganic materials |
| container_volume | 58 |
| creator | Karaeva, M. E. Savinykh, D. O. Orlova, A. I. Khainakov, S. A. Boldin, M. S. Popov, A. A. Nokhrin, A. V. Garcia-Granda, S. Chuvil’deev, V. N. |
| description | —
We have synthesized Na
1 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
and Сa
0.5 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
(X = Mo, W; 0 ≤
x
≤ 0.5) compounds with the NZP structure. Their thermal expansion has been studied in the temperature range 25–800°C using high-temperature X-ray diffraction and shown to have a tendency to decrease as the occupancy of the extraframework sites in their structure decreases. Ceramic samples with a relative density above 97.5% have been prepared from the synthesized phosphate molybdates and phosphate tungstates by spark plasma sintering. Their strength characteristics (microhardness and fracture toughness) have been determined and they have been characterized by hydrolytic stability tests. |
| doi_str_mv | 10.1134/S002016852201006X |
| format | article |
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We have synthesized Na
1 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
and Сa
0.5 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
(X = Mo, W; 0 ≤
x
≤ 0.5) compounds with the NZP structure. Their thermal expansion has been studied in the temperature range 25–800°C using high-temperature X-ray diffraction and shown to have a tendency to decrease as the occupancy of the extraframework sites in their structure decreases. Ceramic samples with a relative density above 97.5% have been prepared from the synthesized phosphate molybdates and phosphate tungstates by spark plasma sintering. Their strength characteristics (microhardness and fracture toughness) have been determined and they have been characterized by hydrolytic stability tests.</description><identifier>ISSN: 0020-1685</identifier><identifier>EISSN: 1608-3172</identifier><identifier>DOI: 10.1134/S002016852201006X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Fracture toughness ; High temperature ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Materials Science ; Microhardness ; Molybdates ; Occupancy ; Plasma sintering ; Sodium zirconium phosphate ; Spark plasma sintering ; Stability tests ; Synthesis ; Thermal expansion ; Tungstates</subject><ispartof>Inorganic materials, 2022, Vol.58 (1), p.78-89</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 0020-1685, Inorganic Materials, 2022, Vol. 58, No. 1, pp. 78–89. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Neorganicheskie Materialy, 2022, Vol. 58, No. 1, pp. 83–94.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-c80b0281217317ef0a4674cb463b8ac513d64d42293bf28194dd2816954109a63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Karaeva, M. E.</creatorcontrib><creatorcontrib>Savinykh, D. O.</creatorcontrib><creatorcontrib>Orlova, A. I.</creatorcontrib><creatorcontrib>Khainakov, S. A.</creatorcontrib><creatorcontrib>Boldin, M. S.</creatorcontrib><creatorcontrib>Popov, A. A.</creatorcontrib><creatorcontrib>Nokhrin, A. V.</creatorcontrib><creatorcontrib>Garcia-Granda, S.</creatorcontrib><creatorcontrib>Chuvil’deev, V. N.</creatorcontrib><title>Synthesis, Temperature Behavior, and Hydrolytic Stability of Na–Zr and Ca–Zr Phosphate Molybdates and Phosphate Tungstates</title><title>Inorganic materials</title><addtitle>Inorg Mater</addtitle><description>—
We have synthesized Na
1 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
and Сa
0.5 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
(X = Mo, W; 0 ≤
x
≤ 0.5) compounds with the NZP structure. Their thermal expansion has been studied in the temperature range 25–800°C using high-temperature X-ray diffraction and shown to have a tendency to decrease as the occupancy of the extraframework sites in their structure decreases. Ceramic samples with a relative density above 97.5% have been prepared from the synthesized phosphate molybdates and phosphate tungstates by spark plasma sintering. Their strength characteristics (microhardness and fracture toughness) have been determined and they have been characterized by hydrolytic stability tests.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Fracture toughness</subject><subject>High temperature</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Microhardness</subject><subject>Molybdates</subject><subject>Occupancy</subject><subject>Plasma sintering</subject><subject>Sodium zirconium phosphate</subject><subject>Spark plasma sintering</subject><subject>Stability tests</subject><subject>Synthesis</subject><subject>Thermal expansion</subject><subject>Tungstates</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Kw0AUhQdRsFYfwN2A20bvTCaTyVKLWqH-QCuImzBJJk1Km8SZiZCN-A6-oU_ipBW6EFfnwPnOvdyL0CmBc0J8djEDoEC4CKgTAP6yhwaEg_B8EtJ9NOhjr88P0ZExSwBggYgG6GPWVbZQpjQjPFfrRmlpW63wlSrke1nrEZZVhiddputVZ8sUz6xMylVpO1zn-EF-f3696g0z_vVPRW2aQlqF710lyZwzG2AXzNtqYWwfHKODXK6MOvnVIXq-uZ6PJ9708fZufDn1UsqF9VIBCVBBKAndPSoHyXjI0oRxPxEyDYifcZYxSiM_yR0XsSxzwqOAEYgk94fobDu30fVbq4yNl3WrK7cyptyPglAEJHAU2VKpro3RKo8bXa6l7mICcf_m-M-bXYduO8ax1ULp3eT_Sz8uX4B7</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Karaeva, M. E.</creator><creator>Savinykh, D. O.</creator><creator>Orlova, A. I.</creator><creator>Khainakov, S. A.</creator><creator>Boldin, M. S.</creator><creator>Popov, A. A.</creator><creator>Nokhrin, A. V.</creator><creator>Garcia-Granda, S.</creator><creator>Chuvil’deev, V. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2022</creationdate><title>Synthesis, Temperature Behavior, and Hydrolytic Stability of Na–Zr and Ca–Zr Phosphate Molybdates and Phosphate Tungstates</title><author>Karaeva, M. E. ; Savinykh, D. O. ; Orlova, A. I. ; Khainakov, S. A. ; Boldin, M. S. ; Popov, A. A. ; Nokhrin, A. V. ; Garcia-Granda, S. ; Chuvil’deev, V. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-c80b0281217317ef0a4674cb463b8ac513d64d42293bf28194dd2816954109a63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Fracture toughness</topic><topic>High temperature</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Microhardness</topic><topic>Molybdates</topic><topic>Occupancy</topic><topic>Plasma sintering</topic><topic>Sodium zirconium phosphate</topic><topic>Spark plasma sintering</topic><topic>Stability tests</topic><topic>Synthesis</topic><topic>Thermal expansion</topic><topic>Tungstates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karaeva, M. E.</creatorcontrib><creatorcontrib>Savinykh, D. O.</creatorcontrib><creatorcontrib>Orlova, A. I.</creatorcontrib><creatorcontrib>Khainakov, S. A.</creatorcontrib><creatorcontrib>Boldin, M. S.</creatorcontrib><creatorcontrib>Popov, A. A.</creatorcontrib><creatorcontrib>Nokhrin, A. V.</creatorcontrib><creatorcontrib>Garcia-Granda, S.</creatorcontrib><creatorcontrib>Chuvil’deev, V. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karaeva, M. E.</au><au>Savinykh, D. O.</au><au>Orlova, A. I.</au><au>Khainakov, S. A.</au><au>Boldin, M. S.</au><au>Popov, A. A.</au><au>Nokhrin, A. V.</au><au>Garcia-Granda, S.</au><au>Chuvil’deev, V. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Temperature Behavior, and Hydrolytic Stability of Na–Zr and Ca–Zr Phosphate Molybdates and Phosphate Tungstates</atitle><jtitle>Inorganic materials</jtitle><stitle>Inorg Mater</stitle><date>2022</date><risdate>2022</risdate><volume>58</volume><issue>1</issue><spage>78</spage><epage>89</epage><pages>78-89</pages><issn>0020-1685</issn><eissn>1608-3172</eissn><abstract>—
We have synthesized Na
1 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
and Сa
0.5 –
x
Zr
2
(PO
4
)
3 –
x
(ХO
4
)
x
(X = Mo, W; 0 ≤
x
≤ 0.5) compounds with the NZP structure. Their thermal expansion has been studied in the temperature range 25–800°C using high-temperature X-ray diffraction and shown to have a tendency to decrease as the occupancy of the extraframework sites in their structure decreases. Ceramic samples with a relative density above 97.5% have been prepared from the synthesized phosphate molybdates and phosphate tungstates by spark plasma sintering. Their strength characteristics (microhardness and fracture toughness) have been determined and they have been characterized by hydrolytic stability tests.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S002016852201006X</doi><tpages>12</tpages></addata></record> |
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| ispartof | Inorganic materials, 2022, Vol.58 (1), p.78-89 |
| issn | 0020-1685 1608-3172 |
| language | eng |
| recordid | cdi_proquest_journals_2639578515 |
| source | Springer Link |
| subjects | Chemistry Chemistry and Materials Science Fracture toughness High temperature Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Microhardness Molybdates Occupancy Plasma sintering Sodium zirconium phosphate Spark plasma sintering Stability tests Synthesis Thermal expansion Tungstates |
| title | Synthesis, Temperature Behavior, and Hydrolytic Stability of Na–Zr and Ca–Zr Phosphate Molybdates and Phosphate Tungstates |
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