Self-assembled platinum-tungsten carbide (Pt-WC)/multi-walled carbon nanotubes (MWCNTs) electrocatalysts for ethanol electro-oxidation in acid medium

The design of a high-performance, durable and low-cost catalyst for direct ethanol fuel cells (DEFCs) applications is an eternal pursuit for researchers in the materials field. In this work, a kind of novel platinum-tungsten carbide (Pt-WC)/multi-walled carbon nanotubes (MWCNTs) electrocatalyst with...

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Bibliographic Details
Published in:Materials express 2022-01, Vol.12 (1), p.90-97
Main Authors: Ai, Tianyu, Zhang, Yi, Lu, Jinlin, Yin, Yansheng
Format: Article
Language:English
Subjects:
Electrocatalyst
Electrocatalysts
Electrochemical analysis
Ethanol
Ethanol Oxidation Reaction
Fuel Cell
Fuel cells
Multi wall carbon nanotubes
Oxidation
Platinum
Self-Assembly
Synergistic effect
Tungsten Carbide
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Summary:The design of a high-performance, durable and low-cost catalyst for direct ethanol fuel cells (DEFCs) applications is an eternal pursuit for researchers in the materials field. In this work, a kind of novel platinum-tungsten carbide (Pt-WC)/multi-walled carbon nanotubes (MWCNTs) electrocatalyst with different WC loadingsis prepared by self-assembly technology for ethanol oxidation reaction (EOR). The electrochemical performance and stability of Pt-WC/MWCNTs electrocatalysts toward EOR are investigated by cyclic voltammetry and chronoamperometry. The mass activity of Pt-WC0.15/MWCNTs electrocatalyst for EOR is 581.94 mA mg-1Pt, which is 1.33 times higher than that of commercial Pt/C (ETEK). The significant enhancement can be attributed to the more exposed active sites and the synergistic effect between Pt and WC. The Pt-WCx/MWCNTs are a kind of excellent and effective electrocatalyst for EOR, which has a broad application prospect in fuel cells.
ISSN:2158-5849
2158-5857
DOI:10.1166/mex.2022.2092