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Composites of NiMoO4@Ni-Co LDH@NiCo2O4 on Ni foam with a rational microscopic morphology for high-performance asymmetric supercapacitors
•NiMoO4@Ni-Co LDH@NiCo2O4 with core-shell structure was successfully designed.•Discuss the influence of electrodeposition time on electrochemical performance.•Asymmetric supercapacitors exhibit a high voltage window of 1.8 V.•NiMoO4@Ni-Co LDH@NiCo2O4 shows a high energy density in asymmetric superca...
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Published in: | Journal of alloys and compounds 2022-05, Vol.902, p.163749, Article 163749 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | •NiMoO4@Ni-Co LDH@NiCo2O4 with core-shell structure was successfully designed.•Discuss the influence of electrodeposition time on electrochemical performance.•Asymmetric supercapacitors exhibit a high voltage window of 1.8 V.•NiMoO4@Ni-Co LDH@NiCo2O4 shows a high energy density in asymmetric supercapacitor.
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The structural stability and high capacity of material enable a wide range of applications for asymmetric supercapacitors. In this work, we design a simple route to synthesize NiMoO4@Ni-Co LDH@NiCo2O4 composites on Ni foam. The NiMoO4@Ni-Co LDH@NiCo2O4 has a stable nanorod/nanosheet core-shell structure. In addition, the NiMoO4@Ni-Co LDH150@NiCo2O4 exhibits a high specific capacity of 1035 C g−1 and retained 80.6% of the original capacity after 5000 cycles. Moreover, the asymmetric supercapacitor is assembled by activated carbon and NiMoO4@Ni-Co LDH150@NiCo2O4 as two electrodes respectively, which shows a high energy density of 66.8 Wh kg−1 at a power density of 900 W kg−1. In the meantime, the asymmetric supercapacitor achieved a high voltage window of 1.8 V. The stable core-shell structure of NiMoO4@Ni-Co LDH@NiCo2O4 achieved a high energy density, which shows great potential for energy storage. |
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ISSN: | 0925-8388 1873-4669 |
DOI: | 10.1016/j.jallcom.2022.163749 |