Optimization of bio-crude yield and its calorific value from hydrothermal liquefaction of bagasse using methanol as co-solvent

• Published in: Energy (Oxford) 2022-04, Vol.244, p.123192, Article 123192
• Main Authors: Yerrayya, A., Nikunj, A., Prashanth, P. Francis, Chakravarthy, S.R., Natarajan, Upendra, Vinu, R.
• Format: Article
• Language: English
• Subjects: Bagasse; Bio-crude; Calorific value; Catalysts; Deoxygenation; Energy recovery; Esters; Factorial design; Hydrothermal liquefaction; Lignocellulose; Liquefaction; Methanol; Optimization; Organic constituents; Phenols; Reaction time; Residues; Resource recovery; Response surface methodology; Selectivity; Solvents; Sustainability; Yield
• ISSN: 0360-5442; 1873-6785
• DOI: 10.1016/j.energy.2022.123192

Hydrothermal liquefaction is a promising resource recovery technique to valorize wet lignocellulosic agro residues. In this study, hydrothermal liquefaction of bagasse was performed at different temperatures (280, 300, 320 °C), reaction times (15, 30, 45 min), and amount of KOH catalyst (5, 7.5, 10 wt%) in the presence of methanol as a co-solvent. The process conditions were optimized using response surface methodology to maximize the yield of bio-crude and its higher heating value (HHV). Maximum bio-crude yield of 36.3 wt% was obtained at 320 °C, 15 min and 10 wt% KOH. The bio-crude yield was found to depend on temperature, amount of KOH, and the interaction of reaction time and amount of KOH. Maximum HHV of bio-crude (34.6 MJ kg−1) was recorded at 320 °C, 45 min and 10 wt% KOH, and this condition corresponded to highest deoxygenation achieved in the bio-crude. The major organic constituents in the bio-crude were cyclo-oxygenates, phenolics, and esters, and their combined selectivity was 78–83%. Maximum energy recovery of 56% was obtained. The energy content of the solid residue was high (∼23 MJ kg−1) at the center point corresponding to 300 °C, 30 min and 7.5 wt% KOH. The process exhibited positive energy gain with favorable sustainability metrics. [Display omitted] •Optimization of operating conditions was performed using 23-full factorial design.•Addition of methanol to water at 50 v/v improved the bio-crude yield upto 36.3 wt%.•At 320 °C, 45 min and 10 wt% KOH loading, HHV of bio-crude was 34.6 MJ kg−1•Bio-crude was rich in phenolics, esters and cyclopentenone derivatives.•Maximum deoxygenation achieved in the bio-crude was 84%.