Nickel-catalyzed alkoxycarbonylation of aryl iodides with 1 atm CO

A nickel-catalyzed alkoxycarbonylation of aromatic iodides with alcohols under atmospheric pressure of carbon monoxide is presented here. This operationally simple protocol allows the facile synthesis of (hetero)aromatic esters, exhibiting broad substrate scope with excellent functional group tolera...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (29), p.4643-4646
Main Authors: Liu, Ning, Wu, Xianqing, Wang, Chenglong, Qu, Jingping, Chen, Yifeng
Format: Article
Language:English
Subjects:
Aliphatic alcohols
Esters
Functional groups
Iodides
Nickel
Phenols
Substrates
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Summary:A nickel-catalyzed alkoxycarbonylation of aromatic iodides with alcohols under atmospheric pressure of carbon monoxide is presented here. This operationally simple protocol allows the facile synthesis of (hetero)aromatic esters, exhibiting broad substrate scope with excellent functional group tolerance. Various primary and secondary aliphatic alcohols as well as phenols are suitable for this transformation. We developed the nickel-catalyzed alkoxycarbonylation of aromatic iodides with alcohols under atmospheric pressure of carbon monoxide.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00876a