Effect of graphite/CeO2 on microstructure and tribological property of plasma cladded Co-based coatings

• Published in: Materials chemistry and physics 2022-03, Vol.280, p.125756, Article 125756
• Main Authors: Li, Dayan, Zhang, Zhixin, Cui, Xiufang, Feng, Litong, Zhang, Dan, Jin, Guo, Liu, Jinna, Zheng, Wei
• Format: Article
• Language: English
• Subjects: CeO2; Cerium oxides; Co-based coatings; Corrosion currents; Corrosion resistance; Corrosive wear; Frictional wear; Graphite; Gray iron; Mechanical properties; Microhardness; Microstructure; Phase composition; Plasma cladding; Protective coatings; Substrates; Tribology; Wear resistance; Workstations
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2022.125756

In this study, graphite/CeO2 reinforced Co-based coatings were prepared on the surface of HT250 gray cast iron by the plasma cladding technology. The influence of graphite and CeO2 on microstructure and properties of Co-based coatings were studied in detail. The phase composition and microstructure of coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The micro-hardness, wear resistance and corrosion resistance of coatings were evaluated using micro-hardness tester, friction wear testing machine and electrochemical workstation. The results showed that the addition of graphite was beneficial to enhance micro-hardness and wear resistance of coatings, but there was still shortcoming in improving corrosion resistance. On this basis, CeO2 was further introduced together with graphite. The microstructure of coatings was found to be more uniform under the synergy of graphite and CeO2. The micro-hardness increased from 684.5 HV0.3 (coatings adding graphite alone) to 767.4 HV0.3 (coatings adding graphite and CeO2), which was 29.7% and 115.1% higher than that of as-cladded coatings and substrate respectively. More importantly, the corrosion current density of coatings was an order of magnitude lower than that of coatings adding graphite alone. Therefore, adding CeO2 together with graphite was beneficial to the synergistic improvement of micro-hardness, wear resistance and corrosion resistance of Co-based coatings. •Co-based coatings adding graphite/CeO2 were prepared by plasma cladding.•The microstructure of coatings became uniform after adding graphite/CeO2.•Wear resistance of coatings adding graphite together with CeO2 was enhanced.•Corrosion resistance of coatings adding graphite together with CeO2 was raised.