Investigation DSC and XRD on the crystallization kinetics in the phosphate Li2O–Li2WO4–TiO2–P2O5 glassy ionic system

• Published in: Journal of materials science. Materials in electronics 2022-04, Vol.33 (11), p.8747-8758
• Main Authors: Es-Soufi, H., Bih, L., Lima, Alan R. F., El Bouari, A., Manoun, B., Hussain, S.
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Composition; Crystal structure; Crystallinity; Crystallization; Data analysis; Glass ceramics; Heating rate; Lithium oxides; Lithium-ion batteries; Materials Science; Molten salt electrolytes; Optical and Electronic Materials; Phases; Phosphates; Phosphorus pentoxide; Product safety; Raman spectroscopy; Rechargeable batteries; Solid electrolytes; Spectrum analysis; Thermal analysis; Titanium dioxide; X-ray diffraction
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-021-06804-7

Solid electrolytes-based lithium phosphates have achieved a great evolution due to the safety problem in the lithium-ion battery. This work targets to investigate the prepared glasses within the 20Li 2 O–(50 − x)Li 2 WO 4 –xTiO 2 –30P 2 O 5 system, with 0 ≤  x  ≤ 15 mol%. The bonds constituting the framework of these glasses were studied by Raman spectroscopy. The data analysis of the chemical durability showed that the dissolution rates depend on the composition of each glass. Thermal analysis by using the DSC technique was used to determine the activation energy of crystallization, it is found in the glassy composition ( x  = 5) that E c = 184.482 kJ/mol. The determinate Avrami parameter is around 1.7, which allows suggesting the mechanism is surface crystallization. The crystallization process of the prepared glasses is carried out by heating samples at a suggested value of temperature around 550 °C for 4 and 12 h, with heating rate of 10 °C/min. The crystallized phases are identified by XRD. The results of the X-ray diffraction analysis confirm that TiO 2 acts mainly as network forming units. The crystalline phases Li 2 WO 4 and Li 4 P 2 O 7 are formed during the crystallization process. The formation of these crystalline phases into the glasses depends on the time of heating at a fixed crystallization temperature. FTIR spectra of the glass–ceramics show nearly the same IR vibrational modes likewise their parent glasses.