Synthesis, Structure, and Properties of Copper(II), Nickel(II), and Cobalt(II) Ketoiminate Chelates. Molecular and Crystal Structures of Bis[2-nitro-3-(8-quinolylimino)prop-1-enoxy]cobalt(II)

β-Aminovinyl ketone (2-nitro-3-(8-quinolylamino)prop-2-enal) was synthesized by condensation of nitromalondialdehyde with 8-aminoquinoline. The reactions of β-aminovinyl ketone with copper, nickel, and cobalt acetates in methanol gave metal complexes. The spectral and magnetic characteristics of pre...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2022-04, Vol.48 (4), p.210-217
Main Authors: Kovaleva, T. V., Uraev, A. I., Lyssenko, K. A., Vlasenko, V. G., Burlov, A. S., Borodkin, G. S., Garnovskii, D. A.
Format: Article
Language:English
Subjects:
Aminoquinolines
Chelates
Chemistry
Chemistry and Materials Science
Cobalt acetates
Cobalt compounds
Coordination compounds
Copper
Crystal structure
Inorganic Chemistry
Ketones
Magnetic properties
Nickel
Physical Chemistry
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Summary:β-Aminovinyl ketone (2-nitro-3-(8-quinolylamino)prop-2-enal) was synthesized by condensation of nitromalondialdehyde with 8-aminoquinoline. The reactions of β-aminovinyl ketone with copper, nickel, and cobalt acetates in methanol gave metal complexes. The spectral and magnetic characteristics of preparatively isolated compounds were studied. The structure of cobalt(II) chelate was determined on the basis of X-ray diffraction study (CIF file CCDC no. 2109263).
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328422040029