Primary thermometers based on sol–gel upconverting Er3+/Yb3+ co-doped yttrium tantalates with high upconversion quantum yield and emission color tunability

• Published in: Journal of sol-gel science and technology 2022-04, Vol.102 (1), p.249-263
• Main Authors: Borges, Fernanda Hediger, Martins, Joana Costa, Caixeta, Fábio José, Pereira, Rafael Ramiro, Carlos, Luis Dias, Ferreira, Rute A. S., Gonçalves, Rogéria Rocha
• Format: Article
• Language: English
• Subjects: Annealing; Ceramics; Chemistry and Materials Science; Color; Composites; Cross relaxation; Crystal structure; Crystallinity; Emission analysis; Energy; Erbium; Fluorides; Glass; Inorganic Chemistry; Luminescence; Materials Science; Measurement techniques; Metal ions; Nanoparticles; Nanotechnology; Natural Materials; Optical and Electronic Materials; Original Paper: Sol–gel and hybrid materials for optical; photonic and optoelectronic applications; Quantum dots; Radiation; Sensitivity; Sol-gel processes; Sol-Gel Research in Latin America; Stabilization; Tantalates; Thermometers; Thermometry; Uncertainty; Upconversion; Ytterbium; Yttrium
• ISSN: 0928-0707; 1573-4846
• DOI: 10.1007/s10971-021-05673-0

This study investigates how rare earth ion (RE 3+ ) concentration affects stabilization of the crystalline structure and infrared-to-visible upconversion (UC) in Er 3+ /Yb 3+ co-doped yttrium tantalates, synthesized by the sol–gel method. Under 980 nm, the samples exhibited intense UC luminescence. The crystalline phases strongly influenced the emission color of UC luminescence. The sample consisting of pure Y 3 TaO 7 phase had a yellowish-green color, but a greener emission appeared in the presence of a small amount of M’-YTaO 4 . Increasing the RE 3+ concentration influences the Y 3 TaO 7 crystalline phase stabilization, as well as in the color tunability, since cross-relaxation processes take place, enhancing red emission intensity. This is the first report of UC quantum yield (UCQY) for yttrium tantalate samples (up to 0.016 ± 0.002%). Samples doped with Er 3+ /Yb 3+ 0.5/1.5 mol % annealed at 900 or 1100 °C were successfully developed as primary thermometers. The temperature of these materials can be predicted without any calibration through the Boltzmann law, using the ratio of the intensity of transitions of Er 3+ . The maximum relative thermal sensitivity was 1.31 ± 0.05% K −1 , which was higher than the sensitivity reported for other oxides. Nanothermometer repeatability was 98.8% and 99.8%, with minimum temperature uncertainty of 0.93 and 0.87 K for samples annealed at 900 and 1100 °C, respectively. The great tunability properties, UCQY values, and nanothermometry results indicated that primary thermometers can be implemented by using Er 3+ /Yb 3+ co-doped yttrium tantalate upconverting nanoparticles for biophotonic applications in temperature sensing and deep tissue imaging. Highlights Y 3 TaO 7 :Er 3+ /Yb 3+ materials were synthetized via the sol–gel method. Upconversion was studied as a function of the doping concentration. The maximum UC quantum yield was 0.016 ± 0.002%. The samples could be successfully applied as primary thermometers. The maximum relative sensitivity was 1.31% K −1 ; the temperature uncertainty was 0.87 K.