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New Data on the Isomorphism in Eudialyte-Group Minerals. ХI: Crystal Structure of a Potentially New Mineral—A Case of Complete Substitution of Fe2+with in the Eudialyte-Type Structure
The crystal structure and crystallochemical features of a Fe-deficient zirconium-rich analog of eudialyte from the Lovozero alkaline massif (Kola peninsula) have been investigated. The unit-cell parameters of the mineral are found to be a = 14.198(1) Å, c = 30.380(1) Å, and V = 5303.9(1) Å 3 ; sp. g...
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| Published in: | Crystallography reports 2022, Vol.67 (2), p.166-171 |
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| Main Authors: | , , , , |
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| Language: | English |
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| container_end_page | 171 |
| container_issue | 2 |
| container_start_page | 166 |
| container_title | Crystallography reports |
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| creator | Rastsvetaeva, R. K. Chukanov, N. V. Pekov, I. V. Varlamov, D. A. Kazheva, O. N. |
| description | The crystal structure and crystallochemical features of a Fe-deficient zirconium-rich analog of eudialyte from the Lovozero alkaline massif (Kola peninsula) have been investigated. The unit-cell parameters of the mineral are found to be
a
= 14.198(1) Å,
c
= 30.380(1) Å, and
V
= 5303.9(1) Å
3
; sp. gr.
R
3
m
. The crystal structure is refined to the final reliability factor
R
= 4.2% in the anisotropic approximation of atomic displacements using 3174 reflections with
F
> 3σ(
F
). The crystallochemical formula of the mineral (
Z
= 3) is [Na
10.38
(H
3
O,H
2
O)
2.79
Ce
0.45
Sr
0.4
K
0.2
][Ca
3.9
Mn
1.2
Fe
0.9
][
VII
Na
V
Zr
0.87
]Zr
3
[Si
1.48
Ti
0.31
Nb
0.21
][Si
24
O
72
](OH)
2.9
(H
2
O)
1.26
(Cl, S)
0.94
(Roman numerals are the coordination numbers (CNs) of cations at the
M
2 key site). The regularities of block isomorphism in the vicinity of the
M
2 site in the structure of the mineral under study and related eudialyte-group minerals are discussed. |
| doi_str_mv | 10.1134/S1063774522020134 |
| format | article |
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a
= 14.198(1) Å,
c
= 30.380(1) Å, and
V
= 5303.9(1) Å
3
; sp. gr.
R
3
m
. The crystal structure is refined to the final reliability factor
R
= 4.2% in the anisotropic approximation of atomic displacements using 3174 reflections with
F
> 3σ(
F
). The crystallochemical formula of the mineral (
Z
= 3) is [Na
10.38
(H
3
O,H
2
O)
2.79
Ce
0.45
Sr
0.4
K
0.2
][Ca
3.9
Mn
1.2
Fe
0.9
][
VII
Na
V
Zr
0.87
]Zr
3
[Si
1.48
Ti
0.31
Nb
0.21
][Si
24
O
72
](OH)
2.9
(H
2
O)
1.26
(Cl, S)
0.94
(Roman numerals are the coordination numbers (CNs) of cations at the
M
2 key site). The regularities of block isomorphism in the vicinity of the
M
2 site in the structure of the mineral under study and related eudialyte-group minerals are discussed.</description><identifier>ISSN: 1063-7745</identifier><identifier>EISSN: 1562-689X</identifier><identifier>DOI: 10.1134/S1063774522020134</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Coordination numbers ; Crystal structure ; Crystallography and Scattering Methods ; Iron ; Isomorphism ; Massifs ; Minerals ; Physics ; Physics and Astronomy ; Reliability aspects ; Structure of Inorganic Compounds ; Unit cell ; Zirconium</subject><ispartof>Crystallography reports, 2022, Vol.67 (2), p.166-171</ispartof><rights>Pleiades Publishing, Inc. 2022. ISSN 1063-7745, Crystallography Reports, 2022, Vol. 67, No. 2, pp. 166–171. © Pleiades Publishing, Inc., 2022. Russian Text © The Author(s), 2022, published in Kristallografiya, 2022, Vol. 67, No. 2, pp. 227–232.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1614-88f76c97283413451c8332b48010beff17adda748f10597480dab1d45c9ff5ed3</citedby><cites>FETCH-LOGICAL-c1614-88f76c97283413451c8332b48010beff17adda748f10597480dab1d45c9ff5ed3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Rastsvetaeva, R. K.</creatorcontrib><creatorcontrib>Chukanov, N. V.</creatorcontrib><creatorcontrib>Pekov, I. V.</creatorcontrib><creatorcontrib>Varlamov, D. A.</creatorcontrib><creatorcontrib>Kazheva, O. N.</creatorcontrib><title>New Data on the Isomorphism in Eudialyte-Group Minerals. ХI: Crystal Structure of a Potentially New Mineral—A Case of Complete Substitution of Fe2+with in the Eudialyte-Type Structure</title><title>Crystallography reports</title><addtitle>Crystallogr. Rep</addtitle><description>The crystal structure and crystallochemical features of a Fe-deficient zirconium-rich analog of eudialyte from the Lovozero alkaline massif (Kola peninsula) have been investigated. The unit-cell parameters of the mineral are found to be
a
= 14.198(1) Å,
c
= 30.380(1) Å, and
V
= 5303.9(1) Å
3
; sp. gr.
R
3
m
. The crystal structure is refined to the final reliability factor
R
= 4.2% in the anisotropic approximation of atomic displacements using 3174 reflections with
F
> 3σ(
F
). The crystallochemical formula of the mineral (
Z
= 3) is [Na
10.38
(H
3
O,H
2
O)
2.79
Ce
0.45
Sr
0.4
K
0.2
][Ca
3.9
Mn
1.2
Fe
0.9
][
VII
Na
V
Zr
0.87
]Zr
3
[Si
1.48
Ti
0.31
Nb
0.21
][Si
24
O
72
](OH)
2.9
(H
2
O)
1.26
(Cl, S)
0.94
(Roman numerals are the coordination numbers (CNs) of cations at the
M
2 key site). The regularities of block isomorphism in the vicinity of the
M
2 site in the structure of the mineral under study and related eudialyte-group minerals are discussed.</description><subject>Coordination numbers</subject><subject>Crystal structure</subject><subject>Crystallography and Scattering Methods</subject><subject>Iron</subject><subject>Isomorphism</subject><subject>Massifs</subject><subject>Minerals</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Reliability aspects</subject><subject>Structure of Inorganic Compounds</subject><subject>Unit cell</subject><subject>Zirconium</subject><issn>1063-7745</issn><issn>1562-689X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1UUtOwzAQjRBIlMIB2FliiVJsx0kcdlVoS6XykVokdpGT2DRVGgfbUZUdh-AKXIJTcAZOgkMrdYFYzWjee_OeZhznHMEBQh65miMYeGFIfIwhhnZy4PSQH2A3oNHzoe0t7Hb4sXOi9QpCSCkiPefznm_ADTMMyAqYJQdTLddS1ctCr0FRgVGTF6xsDXcnSjY1uCsqrlipB-DrY3oNYtVqw0owN6rJTKM4kAIw8CgNr4wVli3oDHaq77f3IYiZ_mXFcl2X3HAwb1JtCtOYwkawwJjjy01hlp19l2gfYdHWfG916hwJm4Sf7WrfeRqPFvGtO3uYTOPhzM1QgIhLqQiDLAox9Yi9i48y6nk4JRQimHIhUMjynIWECgT9yFaYsxTlxM8iIXyee33nYru3VvK14dokK9moylomOPBxgKAXEMtCW1ampNaKi6RWxZqpNkEw6V6U_HmR1eCtRltu9cLVfvP_oh_MkJXJ</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Rastsvetaeva, R. K.</creator><creator>Chukanov, N. V.</creator><creator>Pekov, I. V.</creator><creator>Varlamov, D. A.</creator><creator>Kazheva, O. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2022</creationdate><title>New Data on the Isomorphism in Eudialyte-Group Minerals. ХI: Crystal Structure of a Potentially New Mineral—A Case of Complete Substitution of Fe2+with in the Eudialyte-Type Structure</title><author>Rastsvetaeva, R. K. ; Chukanov, N. V. ; Pekov, I. V. ; Varlamov, D. A. ; Kazheva, O. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1614-88f76c97283413451c8332b48010beff17adda748f10597480dab1d45c9ff5ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Coordination numbers</topic><topic>Crystal structure</topic><topic>Crystallography and Scattering Methods</topic><topic>Iron</topic><topic>Isomorphism</topic><topic>Massifs</topic><topic>Minerals</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Reliability aspects</topic><topic>Structure of Inorganic Compounds</topic><topic>Unit cell</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rastsvetaeva, R. K.</creatorcontrib><creatorcontrib>Chukanov, N. V.</creatorcontrib><creatorcontrib>Pekov, I. V.</creatorcontrib><creatorcontrib>Varlamov, D. A.</creatorcontrib><creatorcontrib>Kazheva, O. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rastsvetaeva, R. K.</au><au>Chukanov, N. V.</au><au>Pekov, I. V.</au><au>Varlamov, D. A.</au><au>Kazheva, O. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Data on the Isomorphism in Eudialyte-Group Minerals. ХI: Crystal Structure of a Potentially New Mineral—A Case of Complete Substitution of Fe2+with in the Eudialyte-Type Structure</atitle><jtitle>Crystallography reports</jtitle><stitle>Crystallogr. Rep</stitle><date>2022</date><risdate>2022</risdate><volume>67</volume><issue>2</issue><spage>166</spage><epage>171</epage><pages>166-171</pages><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>The crystal structure and crystallochemical features of a Fe-deficient zirconium-rich analog of eudialyte from the Lovozero alkaline massif (Kola peninsula) have been investigated. The unit-cell parameters of the mineral are found to be
a
= 14.198(1) Å,
c
= 30.380(1) Å, and
V
= 5303.9(1) Å
3
; sp. gr.
R
3
m
. The crystal structure is refined to the final reliability factor
R
= 4.2% in the anisotropic approximation of atomic displacements using 3174 reflections with
F
> 3σ(
F
). The crystallochemical formula of the mineral (
Z
= 3) is [Na
10.38
(H
3
O,H
2
O)
2.79
Ce
0.45
Sr
0.4
K
0.2
][Ca
3.9
Mn
1.2
Fe
0.9
][
VII
Na
V
Zr
0.87
]Zr
3
[Si
1.48
Ti
0.31
Nb
0.21
][Si
24
O
72
](OH)
2.9
(H
2
O)
1.26
(Cl, S)
0.94
(Roman numerals are the coordination numbers (CNs) of cations at the
M
2 key site). The regularities of block isomorphism in the vicinity of the
M
2 site in the structure of the mineral under study and related eudialyte-group minerals are discussed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1063774522020134</doi><tpages>6</tpages></addata></record> |
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| ispartof | Crystallography reports, 2022, Vol.67 (2), p.166-171 |
| issn | 1063-7745 1562-689X |
| language | eng |
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| subjects | Coordination numbers Crystal structure Crystallography and Scattering Methods Iron Isomorphism Massifs Minerals Physics Physics and Astronomy Reliability aspects Structure of Inorganic Compounds Unit cell Zirconium |
| title | New Data on the Isomorphism in Eudialyte-Group Minerals. ХI: Crystal Structure of a Potentially New Mineral—A Case of Complete Substitution of Fe2+with in the Eudialyte-Type Structure |
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