Adsorption of 2-(pyridin-2-yl)benzothiazoles with terminal thioacetate groups on the gold surface and their complexation with copper(ii) chloride

A method for the preparation of new organic ligands combining in their structure a 2-(pyridin-2-yl)benzothiazole moiety capable of coordinating metal iones and a thioacetate group, which makes it possible to adsorb the obtained compounds on a gold surface, has been developed. Using cyclic voltammetr...

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Bibliographic Details
Published in:Russian chemical bulletin 2022-02, Vol.71 (2), p.260-266
Main Authors: Barskaya, E. S., Abramovich, M. S., Moiseeva, A. A., Chorbu, A. A., Polyakova, M. N., Rzheutsky, A. V., Grigoriev, G. P., Berezina, A. V., Zyk, N. V., Beloglazkina, E. K.
Format: Article
Language:English
Subjects:
Chemisorption
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Coordination compounds
Copper chloride
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Gold
Inorganic Chemistry
Ligands
Organic Chemistry
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Summary:A method for the preparation of new organic ligands combining in their structure a 2-(pyridin-2-yl)benzothiazole moiety capable of coordinating metal iones and a thioacetate group, which makes it possible to adsorb the obtained compounds on a gold surface, has been developed. Using cyclic voltammetry, the possibility of chemisorption of the obtained compounds on the surface of gold electrodes and obtaining complexes of adsorbed ligands with CuCl 2 has been shown.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-022-3406-5