Designing a Network of Crystalline Polymers for a Scalable, Nonfluorinated, Healable and Amphiphobic Solid Slippery Interface

The fluorinated‐liquid infused amphiphobic slippery interfaces exhibiting superior sliding of the beaded oil/water droplets, often suffer from durability and contamination issues. Here, the ability of 1) hexagonal packing of hydrocarbon sides in a selected “comb‐like” polymer and 2) its reversible p...

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Bibliographic Details
Published in:Angewandte Chemie 2022-05, Vol.134 (19), p.n/a
Main Authors: Dhar, Manideepa, Das, Avijit, Parbat, Dibyangana, Manna, Uttam
Format: Article
Language:English
Subjects:
1,4 Conjugate Addition Reaction
Amphiphobic
Chemistry
Comb-Like Polymers
Contamination
Crude oil
Diesel engines
Dodecane
Droplets
Durability
Ethanol
Hexanol
Interfaces
Organic solvents
Phase transitions
Polymer coatings
Polymers
Propanol
Self-Healable Polymers
Sliding
Substrates
Vegetable oils
Water drops
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Description
Summary:The fluorinated‐liquid infused amphiphobic slippery interfaces exhibiting superior sliding of the beaded oil/water droplets, often suffer from durability and contamination issues. Here, the ability of 1) hexagonal packing of hydrocarbon sides in a selected “comb‐like” polymer and 2) its reversible phase transition at 51 °C was rationally exploited to achieve temperature‐assisted rapid (
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.202116763