Interconnected N/P co-doped carbon nanocage as high capacitance electrode material for energy storage devices

• Published in: Nano research 2022-05, Vol.15 (5), p.4068-4075
• Main Authors: Yang, Lei, He, Xiaojun, Wei, Yuchen, Bi, Honghui, Wei, Feng, Li, Hongqiang, Yuan, Changzhou, Qiu, Jieshan
• Format: Article
• Language: English
• Subjects: Atomic/Molecular Structure and Spectra; Biomedicine; Biotechnology; Capacitance; Carbon; Chemical synthesis; Chemistry and Materials Science; Condensed Matter Physics; Electrode materials; Electrodes; Energy storage; Ion adsorption; Life span; Materials Science; Melamine; Nanotechnology; Phytic acid; Research Article; Supercapacitors
• ISSN: 1998-0124; 1998-0000
• DOI: 10.1007/s12274-021-4003-x

Heteroatom doping carbon materials exhibit a huge application potential for energy storage devices (ESDs). Herein, interconnected N/P co-doped carbon nanocage (NP-CNC) was synthesized from pyrene molecules by using nano-MgO as template and melamine-phytic acid supramolecular aggregate as dopant coupled with KOH activation. The as-prepared NP-CNC possesses interconnected nanocages for electron transportation and abundant micropores for ion adsorption. Moreover, co-doped N/P species in NP-CNC provide active sites and additional pseudocapacitance. Consequently, NP-CNC as electrode material for symmetric supercapacitor exhibits a high gravimetric capacitance of 435 F·g −1 at 0.05 A·g −1 , high volumetric capacitance of 274 F·cm −3 at 0.032 A·cm −3 , and long cycle lifespan with 96.1% capacitance retention after 50,000 cycles. Furthermore, NP-CNC as cathode for zinc-ion hybrid supercapacitor delivers satisfactory energy and power densities of 130.6 Wh·kg −1 (82.3 Wh·L −1 ) and 14.4 kW·kg −1 (9.1 kW·L −1 ). This work paves a promising approach to the preparation of high capacitance NP-CNC for ESDs.