Enhanced visible-light-driven photocatalytic and dielectric properties of inorganic–organic hybrid (NiO-g-C3N4) nanocomposite for degradation of rhodamine blue

• Published in: Journal of materials science. Materials in electronics 2022-05, Vol.33 (14), p.10965-10976
• Main Authors: Gayathri, M., Kumar, D. Ranjith, Satheeshkumar, E., Manoj, Devaraj, Kumaresan, A., Arun, A., Jayaprakash, N., Sundaravadivel, E.
• Format: Article
• Language: English
• Subjects: Adsorption; Carbon nitride; Catalytic activity; Characterization and Evaluation of Materials; Charge efficiency; Chemistry and Materials Science; Degradation; Dielectric properties; Heat treatment; Light; Light irradiation; Materials Science; Nanocomposites; Nanoparticles; Nickel oxides; Optical and Electronic Materials; Photocatalysis; Photocatalysts; Rhodamine; Separation; Spectral methods
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-022-08076-1

In this work, NiO NP’s was synthesized by the hydrothermal method and g-C 3 N 4 nanosheets prepared via thermal treatment method, then NiO/g-C 3 N 4 (80:20 wt%) was successfully achieved by a simple mixing method. The optimized NiO/g-C 3 N 4 hybrid nanocomposite was acting as an efficient photocatalyst for degradation of rhodamine blue (RhB) under visible light irradiation. As prepared pristine (NiO and g-C 3 N 4 ) and inorganic–organic hybrid nanocomposite (NiO/g-C 3 N 4 ) materials were characterized by various spectral techniques. From XRD and TEM results, the NiO nanoparticles before and after loading on g-C 3 N 4 surface retained the crystalline phase(fcc) and spherical structure, indicating the synthesis strategy is promising which does not alter its composition and morphology. The adsorption edge of NiO/g-C 3 N 4 was shifted towards lower energy region when compared with pure NiO and g-C 3 N 4 alone reflects that the resulting nanocomposite has larger adsorption efficiency under visible light and thus increases the charge separation efficiency during degradation process. The percentage of degration of RhB for NiO, g-C 3 N 4 and NiO/g-C 3 N 4 hybrid is calculated to be 81, 89 and 94% indicates the effective degradation illuminated under visible light. The enhanced photocatalytic activity of NiO/g-C 3 N 4 photocatalyst probably recognized for the successful interfacial charge separation between NiO and g-C 3 N 4 thus avoids recombination of photoexcited electron–hole pair.