Advanced Ni tar reforming catalysts resistant to syngas impurities: Current knowledge, research gaps and future prospects

• Published in: Fuel (Guildford) 2022-06, Vol.318, p.123602, Article 123602
• Main Authors: Binte Mohamed, Dara Khairunnisa, Veksha, Andrei, Ha, Quan Luu Manh, Chan, Wei Ping, Lim, Teik-Thye, Lisak, Grzegorz
• Format: Article
• Language: English
• Subjects: Alkali metals; Ammonia; Catalysts; Catalytic tar reforming; Deactivation; Gasification; Halide poisoning; Heavy metals; Hydrogen sulfide; Impurities; Nickel; Nickel catalyst; Poisoning; Reforming; Siloxanes; Solid wastes; Sulfur poisoning; Syngas impurities; Synthesis gas; Tar
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2022.123602

[Display omitted] •The effects of syngas impurities on tar reforming Ni catalysts were reviewed.•Poisoning mechanisms on Ni catalyst determined using DFT and experimental studies.•Impurities form inactive Ni, block active sites and induce coking and sintering.•H2S removal, temperature increase, oxidation and steam addition regenerates catalyst.•Design of poison-tolerant Ni catalysts by metal doping and support modification. Catalytic reforming is a promising technology for the removal of tar from syngas. However, due to the presence of other impurities such as H2S, HCl, HBr, siloxanes, alkali metals, and NH3, the lifetime, activity, and stability of commonly used Ni-based catalysts is limited. This review investigates the recent findings related to poisoning effects of both common and under-researched syngas impurities on nickel catalysts and achievements in the synthesis of poison tolerant catalysts. The source and content of impurities produced from the gasification of different feedstock are examined. As current catalysts used for tar reforming require further improvement to ensure tolerance to poisoning, two approaches for catalytic tar reforming gas products from gasification of biomass/solid waste with and without prior syngas pre-treatment are evaluated to emphasize the importance of developing poison-tolerant catalysts. The deactivation mechanisms of Ni catalysts by syngas impurities, regeneration techniques, and strategies for developing poison-tolerant catalysts are reviewed. Finally, limitations of current catalytic tar reforming processes and promising approaches for future works are further discussed.