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On the oximine complexes of transition metals. 106. Spectroscopic and DSC study of some complexes of the types [Cu(DioxH)2] and [CuX2.DioxH2]
Several new complexes of the types [Cu(DioxH)2] and [CuX2·DioxH2] (DioxH2: aliphatic or alicyclic α-dioxime) were obtained and characterized by means of near and far Fourier transformation IR spectroscopy. The thermal decompositions of seven complexes of these types were studied by using DSC measure...
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Published in: | Journal of thermal analysis and calorimetry 1998, Vol.53 (2), p.421-429 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | Several new complexes of the types [Cu(DioxH)2] and [CuX2·DioxH2] (DioxH2: aliphatic or alicyclic α-dioxime) were obtained and characterized by means of near and far Fourier transformation IR spectroscopy. The thermal decompositions of seven complexes of these types were studied by using DSC measurement data. For several decomposition stages, apparent kinetic parameters were derived by means of the nomogram method. |
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ISSN: | 1388-6150 1588-2926 |
DOI: | 10.1023/A:1010129022837 |