Transformations of Isocaryophyllene Diepoxide under Conditions of Homogeneous and Heterogeneous Acid Catalysis

Transformations of isocaryophyllene diepoxide (an isomer of widely spread natural sesquiterpene) were studied in various acidic media under conditions of homogeneous and heterogeneous catalysis. A number of previously unknown compounds were thus obtained. The experimental data were compared with the...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2005-09, Vol.41 (9), p.1280-1285
Main Authors: Salomatina, O. V., Yarovaya, O. I., Korchagina, D. V., Gatilov, Yu. V., Polovinka, M. P., Barkhash, V. A.
Format: Article
Language:English
Subjects:
Catalysis
Organic chemistry
Quantum chemistry
Transformations
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Summary:Transformations of isocaryophyllene diepoxide (an isomer of widely spread natural sesquiterpene) were studied in various acidic media under conditions of homogeneous and heterogeneous catalysis. A number of previously unknown compounds were thus obtained. The experimental data were compared with the results of molecular-mechanics and quantum-chemical simulation of the most probable transformation paths.
ISSN:1070-4280
1608-3393
DOI:10.1007/s11178-005-0335-3