Characteristics of molecular sorption on template containing mesoporous molecular sieves of type MCM-41

Template containing materials of type MCM-41 have properties of microporous substances. On absorption into the micropores of such materials the dependence of the characteristic absorption energies on the molecular mass of the sorptive is extreme, and the specific absorption volume decreases with inc...

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Bibliographic Details
Published in:Theoretical and experimental chemistry 1999, Vol.35 (6), p.343-347
Main Authors: Bobonich, F. M., Kovalenko, A. S., Voloshina, Yu. G., Solomakha, V. N., Korchev, A. S., Filippov, A. P., Il'in, V. G.
Format: Article
Language:English
Subjects:
Absorption
Molar volume
Molecular sieves
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Summary:Template containing materials of type MCM-41 have properties of microporous substances. On absorption into the micropores of such materials the dependence of the characteristic absorption energies on the molecular mass of the sorptive is extreme, and the specific absorption volume decreases with increased molar volume of the sorptive. A model is proposed to explain the peculiarities of the absorption properties of the template containing materials.
ISSN:0040-5760
1573-935X
DOI:10.1007/BF02522794