Solid solutions in the Nd(CCl3COO)3-Sm(CCl3COO)3-H2O system at 298 K

The water-salt system of neodymium and samarium trichloroacetates, Nd(CCl3COO)3-Sm(CCl3COO)3-H2O, has been investigated by the isothermal solubility method at 298 K. The composition of the solid phases is found by the Schreinemakers residues method. The refractive indices, specific volumes, and visc...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2006, Vol.51 (3), p.462-464
Main Authors: Grigor’eva, L. S., Batyreva, V. A.
Format: Article
Language:English
Subjects:
Inorganic chemistry
Liquid phases
Neodymium
Refractivity
Residues
Samarium
Solid phases
Solid solutions
Specific volume
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Summary:The water-salt system of neodymium and samarium trichloroacetates, Nd(CCl3COO)3-Sm(CCl3COO)3-H2O, has been investigated by the isothermal solubility method at 298 K. The composition of the solid phases is found by the Schreinemakers residues method. The refractive indices, specific volumes, and viscosities of the liquid phases and the refractive indices of the solid residues have been determined. Continuous solid solutions are found to form in the system. Some thermodynamic characteristics have been calculated for the solid solutions.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023606030193