Catalytic performance of chloromethane transformation for light olefins production over SAPO-34 with different Si content

AbstactSAPO-34s with low and high Si content were synthesized and characterized by XRD, XRF, NMR, FTIR and TG-DSC. Different Si content generated no apparent difference in XRD patterns and 31P and 27Al MAS NMR spectra. The Si coordination states studied by 29Si MAS NMR predicted the acidity differen...

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Bibliographic Details
Published in:Catalysis letters 2007-03, Vol.114 (1-2), p.30-35
Main Authors: YINGXU WEI, DAZHI ZHANG, YANLI HE, LEI XU, YUE YANG, SU, Bao-Lian, ZHONGMIN LIU
Format: Article
Language:English
Subjects:
Alkenes
Catalysis
Catalysts
Chemical industry
Chemistry
Coke
Exact sciences and technology
General and physical chemistry
Methyl chloride
NMR spectroscopy
Selectivity
Silicon
Spectra
Supply & demand
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Transformations
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Summary:AbstactSAPO-34s with low and high Si content were synthesized and characterized by XRD, XRF, NMR, FTIR and TG-DSC. Different Si content generated no apparent difference in XRD patterns and 31P and 27Al MAS NMR spectra. The Si coordination states studied by 29Si MAS NMR predicted the acidity difference caused by Si incorporation. The absorbance of bridge hydroxyls in FTIR spectra also showed the amount of active sites differed with Si content. Both of the two samples were employed as catalysts in the transformation of chloromethane to light olefins and proved to be very selective catalysts for light olefins production. The influences of Si content on chloromethane conversion and product selectivity were investigated in details. Coke amount and coke species were determined by TG-DSC and FTIR. Coke formation was related to the Si content of SAPO-34 and corresponded to the catalytic performance.
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-007-9038-4