Inhibition activity of ethyleneglycol and its oligomers on tin electrode

Voltammetry and electrochemical impedance spectroscopy were applied to investigate the inhibition activity of ethyleneglycol and its oligomers on tin electrode in strong acidic sulfate solutions. Tetraethyleneglycol was found to be the most active substance among compounds HO–(CH2–CH2–O)m–H (m≤4) th...

Full description

Saved in:
Bibliographic Details
Published in:Journal of solid state electrochemistry 2007-01, Vol.11 (1), p.65-70
Main Authors: Survila, Arvydas, Bražinskienė, Dalia
Format: Article
Language:English
Subjects:
Diffusion rate
Electrochemical impedance spectroscopy
Electrodes
Molecular chains
Oligomers
Polyethers
Tin
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c273t-eb80156bb5ef2a67a0235be7b73d3c34698c414519c636a044209d69670728093
cites cdi_FETCH-LOGICAL-c273t-eb80156bb5ef2a67a0235be7b73d3c34698c414519c636a044209d69670728093
container_end_page 70
container_issue 1
container_start_page 65
container_title Journal of solid state electrochemistry
container_volume 11
creator Survila, Arvydas
Bražinskienė, Dalia
description Voltammetry and electrochemical impedance spectroscopy were applied to investigate the inhibition activity of ethyleneglycol and its oligomers on tin electrode in strong acidic sulfate solutions. Tetraethyleneglycol was found to be the most active substance among compounds HO–(CH2–CH2–O)m–H (m≤4) that retards diffusion-controlled Sn(II) reduction due to its inhibitive adsorption. This rather slow process is controlled both by diffusion and electrosorption steps. A comparison of exchange current densities obtained in the presence of different polyethers shows that the length of the hydrocarbon chain is the main factor responsible for inhibition activity of such substances on tin electrode.
doi_str_mv 10.1007/s10008-005-0070-2
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2665622684</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2665622684</sourcerecordid><originalsourceid>FETCH-LOGICAL-c273t-eb80156bb5ef2a67a0235be7b73d3c34698c414519c636a044209d69670728093</originalsourceid><addsrcrecordid>eNotkE9LAzEUxIMoWKsfwFvAc_TlzybZoxS1hYIXPYdsNtumbDc1SYX99m5bD2_eHIYZ-CH0SOGZAqiXPCloAlBNp4CwKzSjgnMCSurrs2dEC61v0V3OOwCqJIUZWq6GbWhCCXHA1pXwG8qIY4d92Y69H_ymH13ssR1aHErGsQ-buPdpcgMuYcC-966k2Pp7dNPZPvuH_z9H3-9vX4slWX9-rBava-KY4oX4RgOtZNNUvmNWKguMV41XjeItd1zIWjtBRUVrJ7m0IASDupW1VKCYhprP0dOl95Diz9HnYnbxmIZp0jApK8mY1GJK0UvKpZhz8p05pLC3aTQUzAmYuQAzEzBzAmYY_wN_X1y6</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2665622684</pqid></control><display><type>article</type><title>Inhibition activity of ethyleneglycol and its oligomers on tin electrode</title><source>Springer Nature</source><creator>Survila, Arvydas ; Bražinskienė, Dalia</creator><creatorcontrib>Survila, Arvydas ; Bražinskienė, Dalia</creatorcontrib><description>Voltammetry and electrochemical impedance spectroscopy were applied to investigate the inhibition activity of ethyleneglycol and its oligomers on tin electrode in strong acidic sulfate solutions. Tetraethyleneglycol was found to be the most active substance among compounds HO–(CH2–CH2–O)m–H (m≤4) that retards diffusion-controlled Sn(II) reduction due to its inhibitive adsorption. This rather slow process is controlled both by diffusion and electrosorption steps. A comparison of exchange current densities obtained in the presence of different polyethers shows that the length of the hydrocarbon chain is the main factor responsible for inhibition activity of such substances on tin electrode.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-005-0070-2</identifier><language>eng</language><publisher>Heidelberg: Springer Nature B.V</publisher><subject>Diffusion rate ; Electrochemical impedance spectroscopy ; Electrodes ; Molecular chains ; Oligomers ; Polyethers ; Tin</subject><ispartof>Journal of solid state electrochemistry, 2007-01, Vol.11 (1), p.65-70</ispartof><rights>Springer-Verlag 2005.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c273t-eb80156bb5ef2a67a0235be7b73d3c34698c414519c636a044209d69670728093</citedby><cites>FETCH-LOGICAL-c273t-eb80156bb5ef2a67a0235be7b73d3c34698c414519c636a044209d69670728093</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Survila, Arvydas</creatorcontrib><creatorcontrib>Bražinskienė, Dalia</creatorcontrib><title>Inhibition activity of ethyleneglycol and its oligomers on tin electrode</title><title>Journal of solid state electrochemistry</title><description>Voltammetry and electrochemical impedance spectroscopy were applied to investigate the inhibition activity of ethyleneglycol and its oligomers on tin electrode in strong acidic sulfate solutions. Tetraethyleneglycol was found to be the most active substance among compounds HO–(CH2–CH2–O)m–H (m≤4) that retards diffusion-controlled Sn(II) reduction due to its inhibitive adsorption. This rather slow process is controlled both by diffusion and electrosorption steps. A comparison of exchange current densities obtained in the presence of different polyethers shows that the length of the hydrocarbon chain is the main factor responsible for inhibition activity of such substances on tin electrode.</description><subject>Diffusion rate</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrodes</subject><subject>Molecular chains</subject><subject>Oligomers</subject><subject>Polyethers</subject><subject>Tin</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNotkE9LAzEUxIMoWKsfwFvAc_TlzybZoxS1hYIXPYdsNtumbDc1SYX99m5bD2_eHIYZ-CH0SOGZAqiXPCloAlBNp4CwKzSjgnMCSurrs2dEC61v0V3OOwCqJIUZWq6GbWhCCXHA1pXwG8qIY4d92Y69H_ymH13ssR1aHErGsQ-buPdpcgMuYcC-966k2Pp7dNPZPvuH_z9H3-9vX4slWX9-rBava-KY4oX4RgOtZNNUvmNWKguMV41XjeItd1zIWjtBRUVrJ7m0IASDupW1VKCYhprP0dOl95Diz9HnYnbxmIZp0jApK8mY1GJK0UvKpZhz8p05pLC3aTQUzAmYuQAzEzBzAmYY_wN_X1y6</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>Survila, Arvydas</creator><creator>Bražinskienė, Dalia</creator><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20070101</creationdate><title>Inhibition activity of ethyleneglycol and its oligomers on tin electrode</title><author>Survila, Arvydas ; Bražinskienė, Dalia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c273t-eb80156bb5ef2a67a0235be7b73d3c34698c414519c636a044209d69670728093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Diffusion rate</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrodes</topic><topic>Molecular chains</topic><topic>Oligomers</topic><topic>Polyethers</topic><topic>Tin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Survila, Arvydas</creatorcontrib><creatorcontrib>Bražinskienė, Dalia</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Survila, Arvydas</au><au>Bražinskienė, Dalia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Inhibition activity of ethyleneglycol and its oligomers on tin electrode</atitle><jtitle>Journal of solid state electrochemistry</jtitle><date>2007-01-01</date><risdate>2007</risdate><volume>11</volume><issue>1</issue><spage>65</spage><epage>70</epage><pages>65-70</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Voltammetry and electrochemical impedance spectroscopy were applied to investigate the inhibition activity of ethyleneglycol and its oligomers on tin electrode in strong acidic sulfate solutions. Tetraethyleneglycol was found to be the most active substance among compounds HO–(CH2–CH2–O)m–H (m≤4) that retards diffusion-controlled Sn(II) reduction due to its inhibitive adsorption. This rather slow process is controlled both by diffusion and electrosorption steps. A comparison of exchange current densities obtained in the presence of different polyethers shows that the length of the hydrocarbon chain is the main factor responsible for inhibition activity of such substances on tin electrode.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/s10008-005-0070-2</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1432-8488
ispartof Journal of solid state electrochemistry, 2007-01, Vol.11 (1), p.65-70
issn 1432-8488
1433-0768
language eng
recordid cdi_proquest_journals_2665622684
source Springer Nature
subjects Diffusion rate
Electrochemical impedance spectroscopy
Electrodes
Molecular chains
Oligomers
Polyethers
Tin
title Inhibition activity of ethyleneglycol and its oligomers on tin electrode
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T18%3A41%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Inhibition%20activity%20of%20ethyleneglycol%20and%20its%20oligomers%20on%20tin%20electrode&rft.jtitle=Journal%20of%20solid%20state%20electrochemistry&rft.au=Survila,%20Arvydas&rft.date=2007-01-01&rft.volume=11&rft.issue=1&rft.spage=65&rft.epage=70&rft.pages=65-70&rft.issn=1432-8488&rft.eissn=1433-0768&rft_id=info:doi/10.1007/s10008-005-0070-2&rft_dat=%3Cproquest_cross%3E2665622684%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c273t-eb80156bb5ef2a67a0235be7b73d3c34698c414519c636a044209d69670728093%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2665622684&rft_id=info:pmid/&rfr_iscdi=true