Self-Assembly Syntheses and Crystal Structure of a New Organotin(IV) Schiff Base Complex Containing a Novel Sn5O5 Hydrolysis Ladder

A new organotin(IV) Schiff base complex 4 containing a novel Sn5O5 hydrolysis ladder and a disulfide group has been synthesized through a self-assembly reaction. The complex 4 has been characterized by elemental analysis, IR, 1H-, 13C-, and 119Sn-NMR spectra and X-ray crystallography diffraction ana...

Full description

Saved in:
Bibliographic Details
Published in:Journal of inorganic and organometallic polymers and materials 2007-09, Vol.17 (3), p.541-546
Main Authors: Ma, Chunlin, Han, Yawen, Zhang, Rufen
Format: Article
Language:English
Subjects:
Chemical analysis
Crystal structure
Crystallography
Crystals
Hydrogen bonds
Hydrolysis
Imines
NMR
Nuclear magnetic resonance
Self-assembly
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A new organotin(IV) Schiff base complex 4 containing a novel Sn5O5 hydrolysis ladder and a disulfide group has been synthesized through a self-assembly reaction. The complex 4 has been characterized by elemental analysis, IR, 1H-, 13C-, and 119Sn-NMR spectra and X-ray crystallography diffraction analyses. The study of the supramolecular structure of complex 4 found that there exist two kinds of C–H···S and C–H···O intermolecular hydrogen bonds. The two kinds of intermolecular hydrogen bonds force the complex 4 into a 2-dimensional “wave” network. The geometry about each tin atom involved is distorted trigonal bipyramid.
ISSN:1574-1443
1574-1451
DOI:10.1007/s10904-007-9146-z