Flexible and cross-linked N, S co-doped carbon nanofiber nonwovens derived from coal liquefaction residue for high performance supercapacitors

• Published in: Journal of materials science 2022-05, Vol.57 (20), p.9357-9369
• Main Authors: Li, Xiao, Du, Xinyu, Li, Yulin, Tian, Xiaodong, Zheng, Hui, Li, Xuanxuan
• Format: Article
• Language: English
• Subjects: Ammonium sulfate; Carbon fibers; Carbonation; Characterization and Evaluation of Materials; Charge transfer; Chemistry and Materials Science; Classical Mechanics; Coal; Coal liquefaction; Crosslinking; Crystallography and Scattering Methods; Electrodes; Electrospinning; Energy Materials; Liquefaction; Materials Science; Nanofibers; Polyacrylonitrile; Polymer Sciences; Precursors; Residues; Solid Mechanics; Stabilization; Supercapacitors; Terephthalic acid
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-022-07215-7

Flexible, appropriate N, S co-doped electrospinning carbon nanofiber nonwovens with amazing cross-linked architecture (N, S-CLPACF) are successfully achieved in a simple and practicable approach involving the electrospinning of preasphaltene derived from the coal liquefaction residue/polyacrylonitrile/terephthalic acid composite precursor, followed by stabilization, (NH 4 ) 2 SO 4 soaking and carbonation. The degree of cross-link in the structures could be easily adjusted by modulating the temperature during the stabilization. Due to the synergistic action of efficient inter-bonded structures, short charge transfer channels and heteroatom doping, the N, S-CLPACF electrode exhibits a high capacity of 267 F g −1 at 0.2 A g −1 and an outstanding rate capacity of 178 F g −1 at 100 A g −1 . A symmetrical supercapacitor assembled using the N, S-CLPACF electrode delivers a high energy density of 4.7 Wh kg −1 at a power density of 1.2 kW kg −1 and shows a capacitance retention rate of 98% after 10000 cycles at 2 A g −1 . Graphical abstract N, S-CLPACF were successfully achieved in a simple and practicable way through electrospinning preasphaltene derived from coal residue liquefaction/polyacrylonitrile/terephthalic acid composite precursor, followed by stabilization, (NH 4 ) 2 SO 4 soaking and carbonation. The N, S-CLPACF electrode exhibits a high capacity of 267 F g −1 at the current density of 0.2 A g −1 and outstanding rate capacity (178 F g −1 at 100 A g −1 ).