SnBrP‐A SnIP‐type representative in the Sn−Br−P system

One‐dimensional semiconductors are interesting materials due to their unique structural features and anisotropy, which grant them intriguing optical, dielectric and mechanical properties. In this work, we report on SnBrP, a lighter homologue of the first inorganic double helix compound SnIP. This cl...

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Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2022-05, Vol.648 (10), p.n/a
Main Authors: Reiter, Felix, Pielmeier, Markus, Vogel, Anna, Jandl, Christian, Plodinec, Milivoj, Rohner, Christian, Lunkenbein, Thomas, Nisi, Katharina, Holleitner, Alexander, Nilges, Tom
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Language:English
Subjects:
Anisotropy
double helical structure
High temperature
Homology
Mechanical properties
One dimensional compound
Optical properties
Physical properties
Quantum chemistry
semiconductor
Tin
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cited_by cdi_FETCH-LOGICAL-c3577-f41582ff786268949021947caa35a574e4f2a80073691c675a086ff988fe21be3
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container_title Zeitschrift für anorganische und allgemeine Chemie (1950)
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creator Reiter, Felix
Pielmeier, Markus
Vogel, Anna
Jandl, Christian
Plodinec, Milivoj
Rohner, Christian
Lunkenbein, Thomas
Nisi, Katharina
Holleitner, Alexander
Nilges, Tom
description One‐dimensional semiconductors are interesting materials due to their unique structural features and anisotropy, which grant them intriguing optical, dielectric and mechanical properties. In this work, we report on SnBrP, a lighter homologue of the first inorganic double helix compound SnIP. This class of compounds is characterized by intriguing mechanical and electronic properties, featuring a high flexibility without modulation of physical properties. Semiconducting SnBrP can be synthesized from red phosphorus, tin and tin(II)bromide at elevated temperatures and crystallizes as red‐orange, cleavable needles. Raman measurements pointed towards a double helical building unit in SnBrP, showing similarities to the SnIP structure. After taking PL measurements, HR‐TEM, and quantum chemical calculations into account, we were able to propose a sense full structure model for SnBrP.
doi_str_mv 10.1002/zaac.202100347
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source Wiley-Blackwell Read & Publish Collection
subjects Anisotropy
double helical structure
High temperature
Homology
Mechanical properties
One dimensional compound
Optical properties
Physical properties
Quantum chemistry
semiconductor
Tin
title SnBrP‐A SnIP‐type representative in the Sn−Br−P system
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