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(Met)acrylate-Containing Sterically Hindered o-Benzoquinones for free Radical Polymerization
New initiator monomers, derivatives of 3,5-di- tert -butyl- o -benzoquinone containing the 2‑hydroxyethyl methacrylate (HEMA) and pentaerythritol triacrylate (PETA) moieties, have been synthesized. The activity of new o -quinones has been examined in the visible light-induced polymerization (coiniti...
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| Published in: | High energy chemistry 2022-06, Vol.56 (3), p.163-169 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c2314-944b899c409bcbe32f221b27fd161f89004878c885c81c40359bdf166172aeae3 |
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| cites | cdi_FETCH-LOGICAL-c2314-944b899c409bcbe32f221b27fd161f89004878c885c81c40359bdf166172aeae3 |
| container_end_page | 169 |
| container_issue | 3 |
| container_start_page | 163 |
| container_title | High energy chemistry |
| container_volume | 56 |
| creator | Zhiganshina, E. R. Lysenkov, V. S. Lopatina, T. I. Arsenyev, M. V. Chesnokov, S. A. |
| description | New initiator monomers, derivatives of 3,5-di-
tert
-butyl-
o
-benzoquinone containing the 2‑hydroxyethyl methacrylate (HEMA) and pentaerythritol triacrylate (PETA) moieties, have been synthesized. The activity of new
o
-quinones has been examined in the visible light-induced polymerization (coinitiator
N
,
N
-dimethylcyclohexylamine) of oligocarbonate dimethacrylate OCM‑2. The thermal stability of the obtained polymers has been studied. Polymers have been prepared by copolymerization of the synthesized
o
-quinones with HEMA and PETA (initiator azobisisobutyronitrile, 80°C), and the migration of
o
-quinones from the products has been evaluated. |
| doi_str_mv | 10.1134/S0018143922030134 |
| format | article |
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tert
-butyl-
o
-benzoquinone containing the 2‑hydroxyethyl methacrylate (HEMA) and pentaerythritol triacrylate (PETA) moieties, have been synthesized. The activity of new
o
-quinones has been examined in the visible light-induced polymerization (coinitiator
N
,
N
-dimethylcyclohexylamine) of oligocarbonate dimethacrylate OCM‑2. The thermal stability of the obtained polymers has been studied. Polymers have been prepared by copolymerization of the synthesized
o
-quinones with HEMA and PETA (initiator azobisisobutyronitrile, 80°C), and the migration of
o
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tert
-butyl-
o
-benzoquinone containing the 2‑hydroxyethyl methacrylate (HEMA) and pentaerythritol triacrylate (PETA) moieties, have been synthesized. The activity of new
o
-quinones has been examined in the visible light-induced polymerization (coinitiator
N
,
N
-dimethylcyclohexylamine) of oligocarbonate dimethacrylate OCM‑2. The thermal stability of the obtained polymers has been studied. Polymers have been prepared by copolymerization of the synthesized
o
-quinones with HEMA and PETA (initiator azobisisobutyronitrile, 80°C), and the migration of
o
-quinones from the products has been evaluated.</description><subject>Azobisisobutyronitrile</subject><subject>Benzoquinone</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymerization</subject><subject>Free radical polymerization</subject><subject>Free radicals</subject><subject>Initiators</subject><subject>Photochemistry</subject><subject>Physical Chemistry</subject><subject>Polyhydroxyethyl methacrylate</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Quinones</subject><subject>Thermal stability</subject><issn>0018-1439</issn><issn>1608-3148</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLAzEQhYMoWKs_wNuCFz2sZrLZbXLUolaoKFZvwpLNTsqWbVKT7WH7681SwYN4Gpj53pvHI-Qc6DVAxm8WlIIAnknGaEbj5oCMoKAizYCLQzIazulwPyYnIawopXnkRuTz8hm7K6V936oO06mznWpsY5fJokPfaNW2fTJrbI0e68Sld2h37mvbWGcxJMb5xHjE5E3VA5u8urZfR91OdY2zp-TIqDbg2c8ck4-H-_fpLJ2_PD5Nb-epZjFeKjmvhJSaU1npCjNmGIOKTUwNBRghKeViIrQQuRYQqSyXVW2gKGDCFCrMxuRi77vxMRuGrly5rbfxZcmKQuY8BxCRgj2lvQvBoyk3vlkr35dAy6HE8k-JUcP2mhBZu0T_6_y_6Bt8-XLG</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Zhiganshina, E. R.</creator><creator>Lysenkov, V. S.</creator><creator>Lopatina, T. I.</creator><creator>Arsenyev, M. V.</creator><creator>Chesnokov, S. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220601</creationdate><title>(Met)acrylate-Containing Sterically Hindered o-Benzoquinones for free Radical Polymerization</title><author>Zhiganshina, E. R. ; Lysenkov, V. S. ; Lopatina, T. I. ; Arsenyev, M. V. ; Chesnokov, S. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2314-944b899c409bcbe32f221b27fd161f89004878c885c81c40359bdf166172aeae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Azobisisobutyronitrile</topic><topic>Benzoquinone</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymerization</topic><topic>Free radical polymerization</topic><topic>Free radicals</topic><topic>Initiators</topic><topic>Photochemistry</topic><topic>Physical Chemistry</topic><topic>Polyhydroxyethyl methacrylate</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Quinones</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhiganshina, E. R.</creatorcontrib><creatorcontrib>Lysenkov, V. S.</creatorcontrib><creatorcontrib>Lopatina, T. I.</creatorcontrib><creatorcontrib>Arsenyev, M. V.</creatorcontrib><creatorcontrib>Chesnokov, S. A.</creatorcontrib><collection>CrossRef</collection><jtitle>High energy chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhiganshina, E. R.</au><au>Lysenkov, V. S.</au><au>Lopatina, T. I.</au><au>Arsenyev, M. V.</au><au>Chesnokov, S. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>(Met)acrylate-Containing Sterically Hindered o-Benzoquinones for free Radical Polymerization</atitle><jtitle>High energy chemistry</jtitle><stitle>High Energy Chem</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>56</volume><issue>3</issue><spage>163</spage><epage>169</epage><pages>163-169</pages><issn>0018-1439</issn><eissn>1608-3148</eissn><abstract>New initiator monomers, derivatives of 3,5-di-
tert
-butyl-
o
-benzoquinone containing the 2‑hydroxyethyl methacrylate (HEMA) and pentaerythritol triacrylate (PETA) moieties, have been synthesized. The activity of new
o
-quinones has been examined in the visible light-induced polymerization (coinitiator
N
,
N
-dimethylcyclohexylamine) of oligocarbonate dimethacrylate OCM‑2. The thermal stability of the obtained polymers has been studied. Polymers have been prepared by copolymerization of the synthesized
o
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o
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| fulltext | fulltext |
| identifier | ISSN: 0018-1439 |
| ispartof | High energy chemistry, 2022-06, Vol.56 (3), p.163-169 |
| issn | 0018-1439 1608-3148 |
| language | eng |
| recordid | cdi_proquest_journals_2669545118 |
| source | Springer Nature |
| subjects | Azobisisobutyronitrile Benzoquinone Chemistry Chemistry and Materials Science Copolymerization Free radical polymerization Free radicals Initiators Photochemistry Physical Chemistry Polyhydroxyethyl methacrylate Polymerization Polymers Quinones Thermal stability |
| title | (Met)acrylate-Containing Sterically Hindered o-Benzoquinones for free Radical Polymerization |
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