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Crystal growth and characterization of a new quaternary hexagonal nonlinear crystal for the mid-IR: Ba2Ga8GeS16

•Hexagonal Ba2Ga8GeS16 (B2GGS) grown by vertical Bridgman-Stockbarger.•Refractive indices of uniaxial B2GGS measured.•Transmission of B2GGS measured.•Nonlinear coefficient of B2GGS measured.•Second-harmonic generation (SHG) in B2GGS realized. The non-centrosymmetric hexagonal Ba2Ga8GeS16 (B2GGS) cry...

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Bibliographic Details
Published in:Journal of alloys and compounds 2022-06, Vol.907, p.164378, Article 164378
Main Authors: Badikov, Valeriy V., Badikov, Dmitrii V., Shevyrdyaeva, Galina S., Kato, Kiyoshi, Umemura, Nobuhiro, Miyata, Kentaro, Panyutin, Vladimir L., Petrov, Valentin
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Language:English
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Summary:•Hexagonal Ba2Ga8GeS16 (B2GGS) grown by vertical Bridgman-Stockbarger.•Refractive indices of uniaxial B2GGS measured.•Transmission of B2GGS measured.•Nonlinear coefficient of B2GGS measured.•Second-harmonic generation (SHG) in B2GGS realized. The non-centrosymmetric hexagonal Ba2Ga8GeS16 (B2GGS) crystal is grown for the first time with good optical quality by the vertical Bridgman-Stockbarger technique. The linear (transmission, dispersion, and birefringence) and nonlinear (second order susceptibility) properties of this new uniaxial nonlinear crystal for the mid-IR part of the spectrum are studied.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2022.164378