CoFe2O4 surface modification with conducting polypyrrole: employed as a highly active electrocatalyst for oxygen evolution reaction

• Published in: Journal of materials science. Materials in electronics 2022-06, Vol.33 (16), p.13244-13254
• Main Authors: Alwadai, Norah, Manzoor, Sumaira, Ejaz, Syeda Rabia, Khosa, Rabia Yasmin, Aman, Salma, Al-Buriahi, M. S., Alomairy, Sultan, Alrowaili, Z. A., Somaily, H. H., Hayat, Majid
• Format: Article
• Language: English
• Subjects: Alternative energy; Characterization and Evaluation of Materials; Charge transfer; Chemistry and Materials Science; Cobalt ferrites; Conducting polymers; Electrocatalysts; Electrodes; Energy storage; Hydrothermal treatment; Information technology; Materials Science; Metal oxides; Metals; Nitrates; Optical and Electronic Materials; Oxygen evolution reactions; Physics; Polypyrroles; Science; Stainless steel; Water splitting
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-022-08265-y

Electrochemical water splitting could be a potentially viable technique for obtaining the energy from renewable sources. The considerable overpotential demanded for sluggish oxygen evolution reaction (OER), however, prevents broad adoption of this approach. Herein, CoFe 2 O 4 /PPY hybrid is synthesized with a polypyrrole layered on the top of the CoFe 2 O 4 via facile hydrothermal treatment. CoFe 2 O 4 /PPY is a highly efficient electrocatalyst, because it outperforms than pure CoFe 2 O 4 , PPY in terms of OER. CoFe 2 O 4 /PPY OER activities are comparable to those of commercial electrocatalysts. It's worth noting that the CoFe 2 O 4 /PPY hybrid is significantly more stable than the individuals, due to surface coated with PPY, responsible for good conduction of fast-moving electrons. The CoFe 2 O 4 /PPY coupling increases the OER by promoting electron exchange between the PPY layer and the CoFe 2 O 4 reducing the over potential of (274 mV) and also lower the Tafel slope (47 mV/dec) with lower charge transfer resistance (3.15 Ω). According to the findings, on the top of CoFe 2 O 4 , a layer of PPY is applied for the surface modification using a conducting polymer can improve spinel oxides activity for future applications such as photoelectrocatalytic study, for stabilizing the material activity, etc.