Synthesis, structure and properties of trivalent and pentavalent tricarbabismatranes

The first trivalent and pentavalent tricarbabismatranes were synthesized by the reaction of N(CH 2 {2-LiC 6 H 4 }) 3 with BiCl 3 and subsequent reaction with XeF 2 , respectively. The trivalent bismatrane was easily oxidized by air, while the pentavalent bismatrane difluoride was relatively stable t...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2022-06, Vol.58 (46), p.6614-6617
Main Authors: Shimada, Shigeru, Yin, Shuang-Feng, Choe, Yoong-Kee
Format: Article
Language:English
Subjects:
Chemical synthesis
Dichlorides
Difluorides
Room temperature
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Summary:The first trivalent and pentavalent tricarbabismatranes were synthesized by the reaction of N(CH 2 {2-LiC 6 H 4 }) 3 with BiCl 3 and subsequent reaction with XeF 2 , respectively. The trivalent bismatrane was easily oxidized by air, while the pentavalent bismatrane difluoride was relatively stable to air. A similar pentavalent bismatrance dichloride was prone to C-Cl bond reductive elimination even at room temperature. The first trivalent and pentavalent tricarbabismatranes bearing the N(CH 2 C 6 H 4 − ) 3 ligand were synthesized.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00751g