Hydride Intercalation of Lithium into Ni3GaTe2

In order to expand the methods of lithium intercalation into layered multicomponent matrices, the reaction of lithium hydride with layered telluride Ni 3 GaTe 2 through the stage of formation of mechanocomposites has been studied. Intercalation compounds Li x Ni 3 GaTe 2 (0 ≤ x ≤ 0.3) have been show...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2022-05, Vol.67 (5), p.616-621
Main Authors: Buzanov, G. A., Stroganova, E. A., Bykov, A. Yu, Zhizhin, K. Yu, Kuznetsov, N. T.
Format: Article
Language:English
Subjects:
Argon
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Intercalation
Intercalation compounds
Lithium hydrides
Synthesis and Properties of Inorganic Compounds
Tellurides
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Summary:In order to expand the methods of lithium intercalation into layered multicomponent matrices, the reaction of lithium hydride with layered telluride Ni 3 GaTe 2 through the stage of formation of mechanocomposites has been studied. Intercalation compounds Li x Ni 3 GaTe 2 (0 ≤ x ≤ 0.3) have been shown to form when annealing mechanocomposites of the matrix and intercalating agent (LiH) in argon. The channels of hydride ion conversion have been studied and transformations involving the matrix have been described at various temperatures and molar ratios of the matrix and intercalating agent.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023622050035