A NEW POLYMORPH OF THE [ReCl3(MeCN)(PPh3)2] COMPLEX AND ITS OXIDATION PRODUCTS

A new polymorph of the [ReCl 3 (MeCN)(PPh 3 ) 2 ] complex is synthesized and characterized by single crystal X-ray diffraction (XRD). Its recrystallization from the CH 2 Cl 2 / R OH ( R  = Me, Et) mixture is found to result in the formation of the [Re V OCl 2 (O R )(PPh 3 ) 2 ] – its oxidation produ...

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Bibliographic Details
Published in:Journal of structural chemistry 2022, Vol.63 (3), p.470-475
Main Authors: Petrov, P. A., Filippova, E. A., Kompankov, N. B., Sukhikh, T. S., Sokolov, M. N.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Crystal structure
Dichloromethane
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Oxidation
Physical Chemistry
Recrystallization
Single crystals
Solid State Physics
X-ray diffraction
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Summary:A new polymorph of the [ReCl 3 (MeCN)(PPh 3 ) 2 ] complex is synthesized and characterized by single crystal X-ray diffraction (XRD). Its recrystallization from the CH 2 Cl 2 / R OH ( R  = Me, Et) mixture is found to result in the formation of the [Re V OCl 2 (O R )(PPh 3 ) 2 ] – its oxidation product. The crystal structure of the new [ReOCl 2 (OEt)(PPh 3 ) 2 ] polymorph is determined by single crystal XRD.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476622030131