Effect of adding Ag2O to vanadium-containing low-melting glass for low-temperature sealing

Achieving both high water durability and low glass transition temperature is crucial for the practical use of low-melting glass in hermetic sealing. In Ag2O–V2O5–TeO2 glass, we found that the increase in Ag2O content lowers glass transition temperature and improves water durability. Furthermore, the...

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Bibliographic Details
Published in:Journal of the Ceramic Society of Japan 2022/07/01, Vol.130(7), pp.504-508
Main Authors: Aoyagi, Takuya, Onodera, Yohei, Kohara, Shinji, Naito, Takashi, Ina, Toshiaki, Takamatsu, Daiko, Onodera, Taigo, Miyake, Tatsuya, Tachizono, Shinichi, Yoshimura, Kei
Format: Article
Language:English
Subjects:
Atomic properties
Coordination numbers
Durability
Fine structure
Glass transition temperature
Hermetic sealing
Local structure
Low temperature
Oxidation
Oxidation state
Oxygen atoms
Sealing
Tellurium dioxide
Valence
Vanadate glass
Vanadium pentoxide
Water durability
X ray absorption
XAFS
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Summary:Achieving both high water durability and low glass transition temperature is crucial for the practical use of low-melting glass in hermetic sealing. In Ag2O–V2O5–TeO2 glass, we found that the increase in Ag2O content lowers glass transition temperature and improves water durability. Furthermore, the reason for the improvement of water durability is considered to be due to the increase in the coordination number of oxygen atoms around vanadium ions without the change in oxidation state, as shown by X-ray absorption fine structure measurements. We demonstrate that a Ag2O–V2O5–TeO2 glass is a key glass system for low-temperature hermetic sealing.
ISSN:1882-0743
1348-6535
DOI:10.2109/jcersj2.22024