Experimental study of CO2 injectivity impairment in sandstone due to salt precipitation and fines migration

• Published in: Journal of petroleum exploration and production technology 2022-08, Vol.12 (8), p.2191-2202
• Main Authors: Yusof, Muhammad Aslam Md, Neuyam, Yen Adams Sokama, Ibrahim, Mohamad Arif, Saaid, Ismail M., Idris, Ahmad Kamal, Mohamed, Muhammad Azfar
• Format: Article
• Language: English
• Subjects: Brines; Carbon dioxide; Earth and Environmental Science; Earth Sciences; Energy Systems; Flooding; Flow rates; Flow velocity; Gas fields; Geology; Impairment; Industrial and Production Engineering; Industrial Chemistry/Chemical Engineering; Injection; Jamming; Monitoring/Environmental Analysis; Offshore Engineering; Oil and gas fields; Original Paper-Production Geology; Parameters; Permeability; Precipitation; Robustness (mathematics); Salinity; Salt; Salts; Sandstone; Sedimentary rocks; Silica; Silicon dioxide; Sodium; Sodium chloride
• ISSN: 2190-0558; 2190-0566
• DOI: 10.1007/s13202-022-01453-w

Re-injection of carbon dioxide (CO 2 ) in deep saline formation is a promising approach to allow high CO 2 gas fields to be developed in the Southeast Asia region. However, the solubility between CO 2 and formation water could cause injectivity problems such as salt precipitation and fines migration. Although both mechanisms have been widely investigated individually, the coupled effect of both mechanisms has not been studied experimentally. This research work aims to quantify CO 2 injectivity alteration induced by both mechanisms through core-flooding experiments. The quantification injectivity impairment induced by both mechanisms were achieved by varying parameters such as brine salinity (6000–100,000 ppm) and size of fine particles (0–0.015 µm) while keeping other parameters constant, flow rate (2 cm 3 /min), fines concentration (0.3 wt%) and salt type (Sodium chloride). The core-flooding experiments were carried out on quartz-rich sister sandstone cores under a two-step sequence. In order to simulate the actual sequestration process while also controlling the amount and sizes of fines, mono-dispersed silicon dioxide in CO 2 -saturated brine was first injected prior to supercritical CO 2 (scCO 2 ) injection. The CO 2 injectivity alteration was calculated using the ratio between the permeability change and the initial permeability. Results showed that there is a direct correlation between salinity and severity of injectivity alteration due to salt precipitation. CO 2 injectivity impairment increased from 6 to 26.7% when the salinity of brine was raised from 6000 to 100,000 ppm. The findings also suggest that fines migration during CO 2 injection would escalate the injectivity impairment. The addition of 0.3 wt% of 0.005 µm fine particles in the CO 2 -saturated brine augmented the injectivity alteration by 1% to 10%, increasing with salt concentration. Furthermore, at similar fines concentration and brine salinity, larger fines size of 0.015 µm in the pore fluid further induced up to three-fold injectivity alteration compared to the damage induced by salt precipitation. At high brine salinity, injectivity reduction was highest as more precipitated salts reduced the pore spaces, increasing the jamming ratio. Therefore, more particles were blocked and plugged at the slimmer pore throats. The findings are the first experimental work conducted to validate theoretical modelling results reported on the combined effect of salt precipitation and fines mobilisati