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Mechanical and physical characterizations of compatibilizer‐free recycled plastics blend composites modified with carbon nanotube and clay nanofiller
Excessive amount of disposable and reusable plastic wastes has increasingly gained a great environmental concern. This present article aims to investigate the individual effect of multiwalled carbon nanotubes (MWCNTs) and clay loadings at 0.5, 1.0, 2.0, 4.0, and 6.0 phr on the tensile, impact, densi...
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| Published in: | Journal of applied polymer science 2022-08, Vol.139 (32), p.n/a |
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| container_issue | 32 |
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| container_title | Journal of applied polymer science |
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| creator | Nor Arman, Nur Syafiqaz Chen, Ruey Shan Ahmad, Sahrim Shahdan, Dalila |
| description | Excessive amount of disposable and reusable plastic wastes has increasingly gained a great environmental concern. This present article aims to investigate the individual effect of multiwalled carbon nanotubes (MWCNTs) and clay loadings at 0.5, 1.0, 2.0, 4.0, and 6.0 phr on the tensile, impact, density, and water absorption properties of polymer blend made from recycled high‐density polyethylene and recycled polyethylene terephthalate. Both nanocomposites were melt‐blended using a twin screw extruder before compression molding. For MWCNT nanocomposite, 4 phr showed the optimum tensile strength (14.5 MPa), Young's modulus (587.4 MPa), and strain at break (4.2%) as compared to other loadings. For clay nanocomposite system, the optimum tensile properties (13.9 MPa tensile strength, 525.7 MPa Young's modulus, and 4.7% strain) were achieved at 1 phr. The impact strength of the nanocomposites was reduced with both nanofillers' content. With the increment of MWCNT and clay loadings, the percentages of water uptake increased but the values were still considered low ( |
| doi_str_mv | 10.1002/app.52768 |
| format | article |
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The mixture of post‐consumer plastics (from packaging bottles) in nano‐scale filler‐incorporated composites without additional chemical is feasible to achieve certain improvement of mechanical properties. The formulation of the nanocomposite systems was obtained by looking at the tensile, density (remaining its lightweight) and water barrier performance. This could be a practical approach to the abundant plastic wastes issue by giving them a new application as value‐added virgin plastic replacement product.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.52768</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Clay ; Compatibilizers ; composites ; Compressive strength ; Density ; graphene ; Impact strength ; Materials science ; mechanical properties ; Modulus of elasticity ; Multi wall carbon nanotubes ; Nanocomposites ; Polyethylene ; Polyethylene terephthalate ; Polymer blends ; Polymer matrix composites ; Polymers ; Pressure molding ; Tensile properties ; Tensile strength ; thermoplastics ; Twin screw extruders ; Water absorption</subject><ispartof>Journal of applied polymer science, 2022-08, Vol.139 (32), p.n/a</ispartof><rights>2022 Wiley Periodicals LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2278-20e24ce92877b51b1301f008a5bd87a80211689b3141319c7b88e8f7b3b8f9563</citedby><cites>FETCH-LOGICAL-c2278-20e24ce92877b51b1301f008a5bd87a80211689b3141319c7b88e8f7b3b8f9563</cites><orcidid>0000-0001-6621-8545 ; 0000-0002-0580-7837 ; 0000-0002-2713-942X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Nor Arman, Nur Syafiqaz</creatorcontrib><creatorcontrib>Chen, Ruey Shan</creatorcontrib><creatorcontrib>Ahmad, Sahrim</creatorcontrib><creatorcontrib>Shahdan, Dalila</creatorcontrib><title>Mechanical and physical characterizations of compatibilizer‐free recycled plastics blend composites modified with carbon nanotube and clay nanofiller</title><title>Journal of applied polymer science</title><description>Excessive amount of disposable and reusable plastic wastes has increasingly gained a great environmental concern. This present article aims to investigate the individual effect of multiwalled carbon nanotubes (MWCNTs) and clay loadings at 0.5, 1.0, 2.0, 4.0, and 6.0 phr on the tensile, impact, density, and water absorption properties of polymer blend made from recycled high‐density polyethylene and recycled polyethylene terephthalate. Both nanocomposites were melt‐blended using a twin screw extruder before compression molding. For MWCNT nanocomposite, 4 phr showed the optimum tensile strength (14.5 MPa), Young's modulus (587.4 MPa), and strain at break (4.2%) as compared to other loadings. For clay nanocomposite system, the optimum tensile properties (13.9 MPa tensile strength, 525.7 MPa Young's modulus, and 4.7% strain) were achieved at 1 phr. The impact strength of the nanocomposites was reduced with both nanofillers' content. With the increment of MWCNT and clay loadings, the percentages of water uptake increased but the values were still considered low (<0.26% upon 35 days immersion) capacity. These research findings with the effect of nanofiller types and loadings were statistically significant as proven in ANOVA analysis. This study formalizes a chemical‐free environmental strategy to produce nanocomposite as a plastic‐replacement product.
The mixture of post‐consumer plastics (from packaging bottles) in nano‐scale filler‐incorporated composites without additional chemical is feasible to achieve certain improvement of mechanical properties. The formulation of the nanocomposite systems was obtained by looking at the tensile, density (remaining its lightweight) and water barrier performance. This could be a practical approach to the abundant plastic wastes issue by giving them a new application as value‐added virgin plastic replacement product.</description><subject>Clay</subject><subject>Compatibilizers</subject><subject>composites</subject><subject>Compressive strength</subject><subject>Density</subject><subject>graphene</subject><subject>Impact strength</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>Modulus of elasticity</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanocomposites</subject><subject>Polyethylene</subject><subject>Polyethylene terephthalate</subject><subject>Polymer blends</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>Pressure molding</subject><subject>Tensile properties</subject><subject>Tensile strength</subject><subject>thermoplastics</subject><subject>Twin screw extruders</subject><subject>Water absorption</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kL9OwzAQxi0EEqUw8AaWmBjS2k6TOGNV8U8qogPMke2eVVduHOxUVZh4BDbejyfBTViZTnf3--7TfQhdUzKhhLCpaJpJxoqcn6ARJWWRzHLGT9Eo7mjCyzI7RxchbAmhNCP5CH0_g9qI2ihhsajXuNl0oW_i1AvVgjcfojWuDthprNyuiZ001nyA__n80h4Ae1CdshDFVoTWqIClhXjrSLtgWgh459ZGm4gcTLvBSnjpalyL2rV7Cb2xsqLrJ9pYC_4SnWlhA1z91TF6u797XTwmy5eHp8V8mSjGCp4wAmymoGS8KGRGJU0J1YRwkck1LwSPX9OclzKlM5rSUhWSc-C6kKnkuszydIxuhruNd-97CG21dXtfR8uKRWFOSU7LSN0OlPIuBA-6arzZCd9VlFTH3KuYe9XnHtnpwB6Mhe5_sJqvVoPiFz5jiFo</recordid><startdate>20220820</startdate><enddate>20220820</enddate><creator>Nor Arman, Nur Syafiqaz</creator><creator>Chen, Ruey Shan</creator><creator>Ahmad, Sahrim</creator><creator>Shahdan, Dalila</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-6621-8545</orcidid><orcidid>https://orcid.org/0000-0002-0580-7837</orcidid><orcidid>https://orcid.org/0000-0002-2713-942X</orcidid></search><sort><creationdate>20220820</creationdate><title>Mechanical and physical characterizations of compatibilizer‐free recycled plastics blend composites modified with carbon nanotube and clay nanofiller</title><author>Nor Arman, Nur Syafiqaz ; Chen, Ruey Shan ; Ahmad, Sahrim ; Shahdan, Dalila</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2278-20e24ce92877b51b1301f008a5bd87a80211689b3141319c7b88e8f7b3b8f9563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Clay</topic><topic>Compatibilizers</topic><topic>composites</topic><topic>Compressive strength</topic><topic>Density</topic><topic>graphene</topic><topic>Impact strength</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>Modulus of elasticity</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanocomposites</topic><topic>Polyethylene</topic><topic>Polyethylene terephthalate</topic><topic>Polymer blends</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>Pressure molding</topic><topic>Tensile properties</topic><topic>Tensile strength</topic><topic>thermoplastics</topic><topic>Twin screw extruders</topic><topic>Water absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nor Arman, Nur Syafiqaz</creatorcontrib><creatorcontrib>Chen, Ruey Shan</creatorcontrib><creatorcontrib>Ahmad, Sahrim</creatorcontrib><creatorcontrib>Shahdan, Dalila</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nor Arman, Nur Syafiqaz</au><au>Chen, Ruey Shan</au><au>Ahmad, Sahrim</au><au>Shahdan, Dalila</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanical and physical characterizations of compatibilizer‐free recycled plastics blend composites modified with carbon nanotube and clay nanofiller</atitle><jtitle>Journal of applied polymer science</jtitle><date>2022-08-20</date><risdate>2022</risdate><volume>139</volume><issue>32</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>Excessive amount of disposable and reusable plastic wastes has increasingly gained a great environmental concern. This present article aims to investigate the individual effect of multiwalled carbon nanotubes (MWCNTs) and clay loadings at 0.5, 1.0, 2.0, 4.0, and 6.0 phr on the tensile, impact, density, and water absorption properties of polymer blend made from recycled high‐density polyethylene and recycled polyethylene terephthalate. Both nanocomposites were melt‐blended using a twin screw extruder before compression molding. For MWCNT nanocomposite, 4 phr showed the optimum tensile strength (14.5 MPa), Young's modulus (587.4 MPa), and strain at break (4.2%) as compared to other loadings. For clay nanocomposite system, the optimum tensile properties (13.9 MPa tensile strength, 525.7 MPa Young's modulus, and 4.7% strain) were achieved at 1 phr. The impact strength of the nanocomposites was reduced with both nanofillers' content. With the increment of MWCNT and clay loadings, the percentages of water uptake increased but the values were still considered low (<0.26% upon 35 days immersion) capacity. These research findings with the effect of nanofiller types and loadings were statistically significant as proven in ANOVA analysis. This study formalizes a chemical‐free environmental strategy to produce nanocomposite as a plastic‐replacement product.
The mixture of post‐consumer plastics (from packaging bottles) in nano‐scale filler‐incorporated composites without additional chemical is feasible to achieve certain improvement of mechanical properties. The formulation of the nanocomposite systems was obtained by looking at the tensile, density (remaining its lightweight) and water barrier performance. This could be a practical approach to the abundant plastic wastes issue by giving them a new application as value‐added virgin plastic replacement product.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.52768</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-6621-8545</orcidid><orcidid>https://orcid.org/0000-0002-0580-7837</orcidid><orcidid>https://orcid.org/0000-0002-2713-942X</orcidid></addata></record> |
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| subjects | Clay Compatibilizers composites Compressive strength Density graphene Impact strength Materials science mechanical properties Modulus of elasticity Multi wall carbon nanotubes Nanocomposites Polyethylene Polyethylene terephthalate Polymer blends Polymer matrix composites Polymers Pressure molding Tensile properties Tensile strength thermoplastics Twin screw extruders Water absorption |
| title | Mechanical and physical characterizations of compatibilizer‐free recycled plastics blend composites modified with carbon nanotube and clay nanofiller |
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